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Modifying the structure of a photocatalyst to tailor its electronic and physicochemical properties is an effective approach for efficient photocatalysis. Herein, we demonstrate that co-doping non-metal (S) and metal (K) atoms into graphitic carbon nitride (g-C3N4) provides excellent visible-light photocatalytic hydrogen production activity of 8.78 mmol g−1 h−1, which is 98 times higher than that of pristine g-C3N4 (0.09 mmol g−1 h−1). The apparent quantum efficiency of the S+K-co-doped g-C3N4 reaches 70 % at 420 nm. This outstanding photocatalytic performance attributed to an increased specific surface area from 6.78 to 74.23 cm3 g−1, which reduced the recombination of photogenerated charge carriers and enhanced conductivity. Various characterizations are undertaken to elucidate the S+K-co-doped g-C3N4 photocatalytic mechanism. Our work not only demonstrates a facile, eco-friendly and scalable strategy for the synthesis of S+K-co-doped g-C3N4 photocatalysts, but also opens a new avenue for the design of co-doped photocatalysts. © 2020 Elsevier B.V.
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Applied Catalysis B: Environmental
ISSN: 0926-3373
Year: 2020
Volume: 273
1 9 . 5 0 3
JCR@2020
2 0 . 3 0 0
JCR@2023
ESI HC Threshold:160
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
SCOPUS Cited Count: 144
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 3
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