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author:

Chen, Lu (Chen, Lu.) [1] | Zhu, Dongyan (Zhu, Dongyan.) [2] | Li, Jintao (Li, Jintao.) [3] | Wang, Xuxu (Wang, Xuxu.) [4] (Scholars:王绪绪) | Zhu, Jiefang (Zhu, Jiefang.) [5] | Francis, Paul S. (Francis, Paul S..) [6] | Zheng, Yuanhui (Zheng, Yuanhui.) [7] (Scholars:郑远辉)

Indexed by:

EI Scopus SCIE

Abstract:

Modifying the structure of a photocatalyst to tailor its electronic and physicochemical properties is an effective approach for efficient photocatalysis. Herein, we demonstrate that co-doping non-metal (S) and metal (K) atoms into graphitic carbon nitride (g-C3N4) provides excellent visible-light photocatalytic hydrogen production activity of 8.78 mmol g(-1) h(-1), which is 98 times higher than that of pristine g-C3N4 (0.09 mmol g(-1) h(-1)). The apparent quantum efficiency of the S+K-co-doped g-C3N4 reaches 70 % at 420 nm. This outstanding photocatalytic performance attributed to an increased specific surface area from 6.78 to 74.23 cm(3) g(-1), which reduced the recombination of photogenerated charge carriers and enhanced conductivity. Various characterizations are undertaken to elucidate the S+K-co-doped g-C3N4 photocatalytic mechanism. Our work not only demonstrates a facile, eco-friendly and scalable strategy for the synthesis of S+K-co-doped g-C3N4 photocatalysts, but also opens a new avenue for the design of co-doped photocatalysts.

Keyword:

Graphitic carbon nitride Hydrogen evolution Photocatalysis Sulfur/potassium-co-doping

Community:

  • [ 1 ] [Chen, Lu]Fuzhou Univ, Coll Chem, Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Fujian, Peoples R China
  • [ 2 ] [Zhu, Dongyan]Fuzhou Univ, Coll Chem, Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Fujian, Peoples R China
  • [ 3 ] [Li, Jintao]Fuzhou Univ, Coll Chem, Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Fujian, Peoples R China
  • [ 4 ] [Wang, Xuxu]Fuzhou Univ, Coll Chem, Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Fujian, Peoples R China
  • [ 5 ] [Zheng, Yuanhui]Fuzhou Univ, Coll Chem, Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Fujian, Peoples R China
  • [ 6 ] [Zhu, Jiefang]Uppsala Univ, Angstrom Lab, Dept Chem, SE-75121 Uppsala, Sweden
  • [ 7 ] [Francis, Paul S.]Deakin Univ, Fac Sci Engn & Built Environm, Sch Life & Environm Sci, Waurn Ponds, Vic 3216, Australia

Reprint 's Address:

  • 郑远辉

    [Zheng, Yuanhui]Fuzhou Univ, Coll Chem, Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Fujian, Peoples R China;;[Zhu, Jiefang]Uppsala Univ, Angstrom Lab, Dept Chem, SE-75121 Uppsala, Sweden

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Source :

APPLIED CATALYSIS B-ENVIRONMENTAL

ISSN: 0926-3373

Year: 2020

Volume: 273

1 9 . 5 0 3

JCR@2020

2 0 . 3 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:160

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 166

SCOPUS Cited Count: 172

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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