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author:

Lu, Xu-Jie (Lu, Xu-Jie.) [1] | Zhou, Xue-Fei (Zhou, Xue-Fei.) [2] | Zhu, Zheng-Liang (Zhu, Zheng-Liang.) [3] | Sun, Yali (Sun, Yali.) [4] | Tang, Kai (Tang, Kai.) [5] | Lei, Fu-Hou (Lei, Fu-Hou.) [6] | Liu, Zu-Guang (Liu, Zu-Guang.) [7] | Wang, Ting (Wang, Ting.) [8]

Indexed by:

SCIE

Abstract:

The aim of this work is to enable increased production of aromatics by the use of salen-porphyrin complex (ZnPSC6) as a binuclear catalyst for the catalytic oxidation of Indulin AT lignin. Catalytic activity was enhanced by the increase in active sites, as confirmed by the results observed in the conversion of lignin model compounds and Indulin AT lignin compared with processes using the mononuclear complexes Zn(salen) and Zn(Phe-TPP). The yields of long and convoluted aromatics from the catalytic oxidation of Indulin AT lignin with ZnPSC6 reached high values after reaction at 80 degrees C for 24 h. Notably, the formation of vanillin was promoted by the increase in active sites over ZnPSC6. This was followed by a significant decrease of beta-O-4 linkages and refractory condensed substructures in the lignin, induced by ZnPSC6. This may be expected to be an important area for further study.

Keyword:

binuclear complex biomimetic catalysis lignin lignin structure mononuclear complex

Community:

  • [ 1 ] [Lu, Xu-Jie]Hainan Trop Ocean Univ, Sanya, Peoples R China
  • [ 2 ] [Sun, Yali]Hainan Trop Ocean Univ, Sanya, Peoples R China
  • [ 3 ] [Zhou, Xue-Fei]Fuzhou Univ, Fuzhou, Fujian, Peoples R China
  • [ 4 ] [Zhou, Xue-Fei]Nankai Univ, Tianjin, Peoples R China
  • [ 5 ] [Zhou, Xue-Fei]Wuyi Univ, Wuyishan, Peoples R China
  • [ 6 ] [Zhou, Xue-Fei]Kunming Univ Sci & Technol, Kunming, Yunnan, Peoples R China
  • [ 7 ] [Zhu, Zheng-Liang]Kunming Univ Sci & Technol, Kunming, Yunnan, Peoples R China
  • [ 8 ] [Zhou, Xue-Fei]Tsinghua Univ, Beijing, Peoples R China
  • [ 9 ] [Zhou, Xue-Fei]Qilu Univ Technol, Jinan, Shandong, Peoples R China
  • [ 10 ] [Sun, Yali]Chongqing Univ, Chongqing, Peoples R China
  • [ 11 ] [Sun, Yali]Sichuan Univ Sci & Engn, Zigong, Peoples R China
  • [ 12 ] [Tang, Kai]Sichuan Univ Sci & Engn, Zigong, Peoples R China
  • [ 13 ] [Lei, Fu-Hou]Guangxi Univ Nationalities, Nanning, Peoples R China
  • [ 14 ] [Liu, Zu-Guang]Guangxi Univ Nationalities, Nanning, Peoples R China
  • [ 15 ] [Wang, Ting]Guangxi Univ Nationalities, Nanning, Peoples R China

Reprint 's Address:

  • [Sun, Yali]Chongqing Univ, Chongqing, Peoples R China;;[Sun, Yali]Sichuan Univ Sci & Engn, Zigong, Peoples R China

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Source :

DREWNO

ISSN: 1644-3985

Year: 2019

Issue: 203

Volume: 62

Page: 67-80

0 . 5 7 8

JCR@2019

0 . 8 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:236

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 5

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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