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[期刊论文]

Synthesis and crystal structure of binuclear copper (II) complex containing (dimethylaminomethyl)ferrocene

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author:

Huang, Z.-X. (Huang, Z.-X..) [1] | Wang, X.-L. (Wang, X.-L..) [2] | Liu, S.-X. (Liu, S.-X..) [3]

Indexed by:

Scopus CSCD

Abstract:

A binuclear complex including ferrocenyl, Cu2{Fe(C 5H5)[C5H4CH2N(CH 3)2]}2 (CH3COO)4, was synthesized and characterized by X-ray diffraction. The title complex crystallizes in triclinic, space group P1 with a = 8.2779(8), b = 9.4830(8), c = 12.262(1) Å, α = 81.079(5), β = 80.620(4), γ = 78.960(4)°, V = 924.4(1) Å3, Z = 1, C34H 46Cu2Fe2N2O8, M r = 849.51, Dc = 1.526 g/cm3, λ(MoKα) = 0.71073 Å, μ = 1.954 mm-1, F(000) = 438, R = 0.0297 and wR = 0.0901. Both cyclopentadienyl rings in each dmaf (dmaf = (dimethylaminomethyl)ferrocene, Fe(C5H5)-[C 5H4CH2N(CH3)2]) have an eclipsed conformation. The binuclear molecule has a crystallographic centrosymmetry; four acetates and two Cu atoms form a cage structure with the distance between two neighboring Cu atoms of 2.655(1) Å.

Keyword:

(Dimethylaminomethyl)- ferrocene; Binuclear complex; Copper complex; Crystal structure

Community:

  • [ 1 ] [Huang, Z.-X.]Department of Chemistry, Fuzhou University, Fuzhou 350002, China
  • [ 2 ] [Wang, X.-L.]Department of Chemistry, Fuzhou University, Fuzhou 350002, China
  • [ 3 ] [Liu, S.-X.]Department of Chemistry, Fuzhou University, Fuzhou 350002, China

Reprint 's Address:

  • [Huang, Z.-X.]Department of Chemistry, Fuzhou University, Fuzhou 350002, China

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Source :

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY

ISSN: 0254-5861

CN: 35-1112/TQ

Year: 2002

Issue: 5

Volume: 21

Page: 505-508

0 . 3 2 4

JCR@2002

5 . 9 0 0

JCR@2023

JCR Journal Grade:4

Cited Count:

WoS CC Cited Count:

30 Days PV: 0

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