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Abstract:
A binuclear complex including ferrocenyl, Cu2{Fe(C 5H5)[C5H4CH2N(CH 3)2]}2 (CH3COO)4, was synthesized and characterized by X-ray diffraction. The title complex crystallizes in triclinic, space group P1 with a = 8.2779(8), b = 9.4830(8), c = 12.262(1) Å, α = 81.079(5), β = 80.620(4), γ = 78.960(4)°, V = 924.4(1) Å3, Z = 1, C34H 46Cu2Fe2N2O8, M r = 849.51, Dc = 1.526 g/cm3, λ(MoKα) = 0.71073 Å, μ = 1.954 mm-1, F(000) = 438, R = 0.0297 and wR = 0.0901. Both cyclopentadienyl rings in each dmaf (dmaf = (dimethylaminomethyl)ferrocene, Fe(C5H5)-[C 5H4CH2N(CH3)2]) have an eclipsed conformation. The binuclear molecule has a crystallographic centrosymmetry; four acetates and two Cu atoms form a cage structure with the distance between two neighboring Cu atoms of 2.655(1) Å.
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Source :
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
ISSN: 0254-5861
CN: 35-1112/TQ
Year: 2002
Issue: 5
Volume: 21
Page: 505-508
0 . 3 2 4
JCR@2002
5 . 9 0 0
JCR@2023
JCR Journal Grade:4
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