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author:

Lin, Zhenyu (Lin, Zhenyu.) [1] (Scholars:林振宇) | Sun, Jianjun (Sun, Jianjun.) [2] (Scholars:孙建军) | Chen, Jinhua (Chen, Jinhua.) [3] | Guo, Liang (Guo, Liang.) [4] | Chen, Guonan (Chen, Guonan.) [5] (Scholars:陈国南)

Indexed by:

EI Scopus SCIE

Abstract:

In this paper, an ECL detection system equipped with an electrically heating controlled cylindrical microelectrode (HME) was used to study the ECL behavior of lucigenin. The ECL intensity of lucigenin would be increased at elevated electrode temperature but the noise had not been increased. It was found that ECL intensity at higher temperature of electrode surface (80 degrees C) was more than two magnitudes stronger than that at the room temperature (22 degrees C). The detection limit for ECL of lucigenin on a HME is much lower than that on an electrode without heating, based on which, it is possible to establish a more sensitive method for measurement of ECL by using a HME. The heating of electrode has been used to renew the electrode, which avoid the tedious work for refreshing the electrode surface. The reproducibility of lucigenin ECL system at HME is satisfactory. (c) 2006 Elsevier B.V.All rights reserved.

Keyword:

electrochemiluminescence heating microelectrode lucigenin

Community:

  • [ 1 ] Fuzhou Univ, Dept Chem, Fujian 350002, Peoples R China
  • [ 2 ] Fuzhou Univ, Minist Educ, Key Lab Anal & Detect Technol Food Safety, Fujian 350002, Peoples R China

Reprint 's Address:

  • 陈国南

    [Chen, Guonan]Fuzhou Univ, Dept Chem, Fujian 350002, Peoples R China

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Source :

ELECTROCHEMISTRY COMMUNICATIONS

ISSN: 1388-2481

Year: 2007

Issue: 2

Volume: 9

Page: 269-274

4 . 1 8 6

JCR@2007

4 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count: 36

SCOPUS Cited Count: 37

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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