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author:

Xie, Li-Li (Xie, Li-Li.) [1] (Scholars:谢莉莉) | Favre-Reguillon, Alain (Favre-Reguillon, Alain.) [2] | Wang, Xu-Xu (Wang, Xu-Xu.) [3] (Scholars:王绪绪) | Fu, Xianzhi (Fu, Xianzhi.) [4] (Scholars:付贤智) | Vrinat, Michel (Vrinat, Michel.) [5] | Lemaire, Marc (Lemaire, Marc.) [6]

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EI Scopus SCIE

Abstract:

The extraction of trace polar compounds, among them neutral nitrogen-containing compounds (N-compounds), has received much attention from refiners because of their inhibiting effect on the hydrodesulfurization (HDS) process. Recently, we have shown that chloride-based ionic liquids (ILs) can selectively extract N-compounds from straight-run diesel feeds. However, the measurable solubility of ILs in hydrocarbon fuel is not a desired outcome of the process. Thus, the covalent binding of ILs moieties on polymers was studied. Starting from Merrifield resin, three resins were prepared with imidazolium, pyridinium, and triethylammonium chloride functionality. The resins were evaluated using a synthetic solution with dibenzothiophene and carbazole as model compounds, and a high selectivity for N-compounds was found. Imidazolium and pyridinium resins were then further evaluated using straight-run diesel feed containing 13400 ppm S and 105 ppm N. The selectivity toward N-compounds was comparable to the selectivity observed with ILs. Moreover, the resins could be easily regenerated using a protic solvent like methanol.

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Community:

  • [ 1 ] [Favre-Reguillon, Alain]Univ Lyon 1, CNRS, Conservatoire Natl Arts & Metiers, Lab Transformat Chim & Pharmaceut,UMR7084,UMR5246, F-75003 Paris, France
  • [ 2 ] [Favre-Reguillon, Alain]ICBMS, Lab Catalyse & Synth Organ, UMR 5246, F-69622 Villeurbanne, France
  • [ 3 ] [Favre-Reguillon, Alain]Univ Lyon 1, IRCELYON, CNRS, UMR5256, F-69626 Villeurbanne, France
  • [ 4 ] [Xie, Li-Li]Fuzhou Univ, Res Inst Photocatalysis, Fuzhou 350002, Peoples R China
  • [ 5 ] [Wang, Xu-Xu]Fuzhou Univ, Res Inst Photocatalysis, Fuzhou 350002, Peoples R China
  • [ 6 ] [Fu, Xianzhi]Fuzhou Univ, Res Inst Photocatalysis, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • [Favre-Reguillon, Alain]Univ Lyon 1, CNRS, Conservatoire Natl Arts & Metiers, Lab Transformat Chim & Pharmaceut,UMR7084,UMR5246, 2 Rue Conte, F-75003 Paris, France

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Source :

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

ISSN: 0888-5885

Year: 2009

Issue: 8

Volume: 48

Page: 3973-3977

1 . 7 5 8

JCR@2009

3 . 8 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:2

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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