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author:

Xie, L.-L. (Xie, L.-L..) [1] | Favre-Reguillon, A. (Favre-Reguillon, A..) [2] | Wang, X.-X. (Wang, X.-X..) [3] | Fu, X. (Fu, X..) [4] | Vrinat, M. (Vrinat, M..) [5] | Lemaire, M. (Lemaire, M..) [6]

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Scopus

Abstract:

The extraction of trace polar compounds, among them neutral nitrogen-containing compounds (N-compounds), has received much attention from refiners because of their inhibiting effect on the hydrodesulfurization (HDS) process. Recently, we have shown that chloride-based ionic liquids (ILs) can selectively extract N-compounds from straight-run diesel feeds. However, the measurable solubility of ILs in hydrocarbon fuel is not a desired outcome of the process. Thus, the covalent binding of ILs moieties on polymers was studied. Starting from Merrifield resin, three resins were prepared with imidazolium, pyridinium, and triethylammonium chloride functionality. The resins were evaluated using a synthetic solution with dibenzothiophene and carbazole as model compounds, and a high selectivity for N-compounds was found. Imidazolium and pyridinium resins were then further evaluated using straight-run diesel feed containing 13400 ppm S and 105 ppm N. The selectivity toward N-compounds was comparable to the selectivity observed with ILs. Moreover, the resins could be easily regenerated using a protic solvent like methanol. © 2009 American Chemical Societ.

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Community:

  • [ 1 ] [Xie, L.-L.]ICBMS, Institut de Chimie et Biochimie Moléculaires et Supramoléculairess-UMR 5246, Laboratoire de Catalyse et Synthese Organique, 43 boulevard du 11 novembre 1918, Villeurbanne, F-69622, France
  • [ 2 ] [Xie, L.-L.]Research Institute of Photocatalysis, Fuzhou University, 523 Gong Ye Road, 350002 Fuzhou, China
  • [ 3 ] [Favre-Reguillon, A.]ICBMS, Institut de Chimie et Biochimie Moléculaires et Supramoléculairess-UMR 5246, Laboratoire de Catalyse et Synthese Organique, 43 boulevard du 11 novembre 1918, Villeurbanne, F-69622, France
  • [ 4 ] [Favre-Reguillon, A.]CNRS, UMR5246, ConserVatoire National des Arts et Métiers, 2 rue Conté, Paris, F-75003, France
  • [ 5 ] [Wang, X.-X.]Research Institute of Photocatalysis, Fuzhou University, 523 Gong Ye Road, 350002 Fuzhou, China
  • [ 6 ] [Fu, X.]Research Institute of Photocatalysis, Fuzhou University, 523 Gong Ye Road, 350002 Fuzhou, China
  • [ 7 ] [Vrinat, M.]IRCELYON, CNRS, Université Lyon 1, 2 aVenue Albert Einstein, Villeurbanne, F-69626, France
  • [ 8 ] [Lemaire, M.]ICBMS, Institut de Chimie et Biochimie Moléculaires et Supramoléculairess-UMR 5246, Laboratoire de Catalyse et Synthese Organique, 43 boulevard du 11 novembre 1918, Villeurbanne, F-69622, France

Reprint 's Address:

  • [Favre-Reguillon, A.]ICBMS, Institut de Chimie et Biochimie Moléculaires et Supramoléculairess-UMR 5246, Laboratoire de Catalyse et Synthese Organique, 43 boulevard du 11 novembre 1918, Villeurbanne, F-69622, France

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Source :

Industrial and Engineering Chemistry Research

ISSN: 0888-5885

Year: 2009

Issue: 8

Volume: 48

Page: 3973-3977

1 . 7 5 8

JCR@2009

3 . 8 0 0

JCR@2023

JCR Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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