A　new　hybrid　coordination　polymer　{[Cu(II)(2,2＇-bipy)(3)][Pb2I6]}(n)　(1)　was　synthesized　by　the　reaction　of　Cu(NO3)(2),　2,2＇-bipy,　PbI2　and　NaI　in　DMF/DMSO　mixed　solvent.　As　revealed　by　X-ray　structural　analysis,　1　consists　of　[Pb2I6](n)(2n-)　polyanions　and　discrete　[Cu(II)(2,2＇-bipy)(3)](2+)　structure-directing　agent　cations.　The　polymeric　negative　chain　[Pb2I6](n)(2-)　is　built　up　by　face-sharing　of　PbI6　octahedra.　Structure-directing　reagent　cations　and　polymeric　negative　chains　are　in　combination　with　each　other　by　static　attracting　force　to　form　so-called　hybrid　structure.　Experimental　and　theoretical　optical　property　investigations　indicate　that　1　possesses　semiconductor　property.　DFT　calculation　was　executed　to　probe　the　electronic　structure　of　1.　To　our　interest,　when　using　both　second　metal　and　pi　system　as　electronic　tuning　species,　conjugated　system　is　more　preferable.