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Hydrothermal reactions of substituted phthalic acid with lanthanide salts lead to two kinds of coordination polymers containing linear lanthanide-oxygen clusters, where the different coordination patterns are attributed to the effect of lanthanide contraction. Five coordination polymers containing linear lanthanide-oxygen clusters 1-5 have been synthesized by a hydrothermal reaction of 3-(quinolin-8-yloxy) phthalic acid ((HL)-L-2) with the respective lanthanide salt. The X-ray single crystal structural analyses revealed that these five crystalline materials belong to two isostructures with formulas [LnHL(2)(H2O)(2)](n) (Ln1, where Ln = La 1, Ce 2, Pr 3) and [Ln(HL)(L)(H2O)](n) (Ln2, where Ln = Nd 4, Sm 5), respectively, which are attributed to the effect of lanthanide contraction. In both structures, the lanthanide cations were bridged by two carboxyl groups of L2- through Ln-O bonds to form 1-D linear lanthanide-oxygen clusters, which were further connected by intermolecular pi-pi stacking interactions between quinolinyl units to generate 3-D supramolecular polymers with moderate luminescence and high thermal stability.
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JOURNAL OF COORDINATION CHEMISTRY
ISSN: 0095-8972
Year: 2014
Issue: 21
Volume: 67
Page: 3542-3550
2 . 0 1 2
JCR@2014
2 . 2 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:268
JCR Journal Grade:2
CAS Journal Grade:3
Cited Count:
WoS CC Cited Count: 5
SCOPUS Cited Count: 5
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 0
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