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Abstract:
A novel squaraine-based chemosensor SQ-1 has been synthesized, and its sensing behavior toward various metal ions was investigated by UV- vis and fluorescence spectroscopies. In AcOH-H2O (40:60, v/v) solution, Hg2+ ions coordinate with SQ-1 causing a deaggregation which induces a visual color and absorption spectral changes as well as strong fluorescence. In contrast, the addition of other metals (e.g., Pb2+, Cd2+, Cu2+, Zn2+, Al3+, Ni2+, Co2+, Fe3+, Ca2+, K+, Mg2+, Na+, and Ag+) does not induce these changes at all. Thus SQ-1 is a specific Hg2+ sensing agent due to the inducing deaggregation of the dye molecule by Hg2+.
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ORGANIC LETTERS
ISSN: 1523-7060
Year: 2011
Issue: 5
Volume: 13
Page: 1162-1165
5 . 8 6 2
JCR@2011
4 . 9 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 198
SCOPUS Cited Count: 205
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
Affiliated Colleges: