Two　new　heterometallic　complexes,　[Bi(phen)I4Ag(phen)](n)　(1)　and　[Pb(bipy)Ag3I5](n)　(2)　(phen　=　1,10-phenanthroline,　bipy　=　2,2＇-bipyridine),　have　been　synthesized,　significant　for　incorporation　of　heavy　p-block　metals　(Pb　and　Bi)　into　iodoargentate　frameworks　to　get　heterometallic　complexes.　Complex　1　could　be　described　as　the　combination　of　Ag(phen)I-4　and　Bi(phen)I-4　octahedra　by　edge-sharing　and　2　is　constructed　from　(Ag3I5)(n)(2n-)　and　[Pb(2,2＇-bipy)](2+)　by　Pb-I　covalent　bonds.　Their　optical　band　gaps,　fluorescences,　and　thermal　behaviors　are　also　discussed.