Introducing p-block metals into iodoargentates: Structures and properties of two new heterometallic hybrids - Details

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Abstract：

Two　new　heterometallic　complexes,　[Bi(phen)I　4Ag(phen)]　n　(1)　and　[Pb(bipy)Ag　3I　5]　n　(2)　(phen=1,10-phenanthroline,　bipy=2,2′-bipyridine),　have　been　synthesized,　significant　for　incorporation　of　heavy　p-block　metals　(Pb　and　Bi)　into　iodoargentate　frameworks　to　get　heterometallic　complexes.　Complex　1　could　be　described　as　the　combination　of　Ag(phen)I　4　and　Bi(phen)I　4　octahedra　by　edge-sharing　and　2　is　constructed　from　(Ag　3I　5)　n　2-　and　[Pb(2,2′-bipy)]　2+　by　Pb-I　covalent　bonds.　Their　optical　band　gaps,　fluorescences,　and　thermal　behaviors　are　also　discussed.　©　2012　Taylor　and　Francis.

Keyword：

Heterometallic iodoargentate; Hybrid semiconductor; Optical adsorption

Community：

[ 1 ] [Li, H.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, China
[ 2 ] [Li, H.]State Key Laboratory Breeding Base of Photocatalysis, Fuzhou University, Fuzhou 350002, China
[ 3 ] [Li, J.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, China
[ 4 ] [Wang, M.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, China
[ 5 ] [Huang, S.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, China
[ 6 ] [Gong, A.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, China
[ 7 ] [Wu, H.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, China
[ 8 ] [Chen, Z.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, China
[ 9 ] [Chen, Z.]State Key Laboratory Breeding Base of Photocatalysis, Fuzhou University, Fuzhou 350002, China

Reprint 's Address：

[Li, H.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, China

Email：

lihh@fzu.edu.cn

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Source ：

Journal of Coordination Chemistry

ISSN： 0095-8972

Year： 2012

Issue： 21

Volume： 65

Page： 3851-3859

1 . 8 0 1

JCR@2012

2 . 2 0 0

JCR@2023

JCR Journal Grade：2

CAS Journal Grade：4

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SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

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Chinese Cited Count：

30 Days PV： 1

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