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author:

Zhang Yanjie (Zhang Yanjie.) [1] | Zhan Yingying (Zhan Yingying.) [2] (Scholars:詹瑛瑛) | Cao Yanning (Cao Yanning.) [3] (Scholars:曹彦宁) | Chen Chongqi (Chen Chongqi.) [4] (Scholars:陈崇启) | Lin Xingyi (Lin Xingyi.) [5] (Scholars:林性贻) | Zheng Qi (Zheng Qi.) [6] (Scholars:郑起)

Indexed by:

EI Scopus SCIE PKU CSCD

Abstract:

Au/ZrO2 catalysts with a nominal gold loading of 1.0% were prepared by a deposition-precipitation method employing a series of ZrO2 samples synthesized by a convenient hydrothermal route as supports. These catalysts were evaluated for low-temperature water-gas shift reaction under a model reformed methanol gas atmosphere. The effect of the hydrothermal synthesis temperature of zirconia on the catalytic activity of Au/ZrO2 was investigated. The optimal hydrothermal synthesis temperature of ZrO2 was 150 degrees C. The corresponding catalyst offers a CO conversion of 87% at a reaction temperature of 240 degrees C, which is significantly higher than that of the previously reported Au/Fe2O3, Au/CeO2, and Au/CeZrO4 catalysts. The Au/ZrO2 catalysts were characterized by X-ray diffraction, atomic absorption spectrometry, N-2-physisorption, and scanning electron microscopy. The results indicate that the catalytic performance of the Au/ZrO2 catalysts is mainly influenced by the morphology and pore structure of the ZrO2 that was hydrothermally synthesized at different temperatures. A uniform nanodisk morphology and increase in the pore volume and pore diameter of the ZrO2 particles lead to a higher catalytic activity of the Au/ZrO2 catalyst.

Keyword:

gold hydrothermal method hydrothermal synthesis temperature supported catalyst water-gas shift reaction zirconia

Community:

  • [ 1 ] [Zhang Yanjie]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Zhan Yingying]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Cao Yanning]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Chen Chongqi]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Lin Xingyi]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Zheng Qi]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address:

  • 郑起

    [Zheng Qi]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China

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Source :

CHINESE JOURNAL OF CATALYSIS

ISSN: 0253-9837

CN: 21-1601/O6

Year: 2012

Issue: 2

Volume: 33

Page: 230-236

1 . 3 0 4

JCR@2012

1 5 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:2

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 17

SCOPUS Cited Count: 21

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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