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author:

Yang Shenyong (Yang Shenyong.) [1] | Zhan Yingying (Zhan Yingying.) [2] (Scholars:詹瑛瑛) | Chen Chongqi (Chen Chongqi.) [3] (Scholars:陈崇启) | Cao Yanning (Cao Yanning.) [4] (Scholars:曹彦宁) | Lin Xingyi (Lin Xingyi.) [5] (Scholars:林性贻) | Zheng Qi (Zheng Qi.) [6] (Scholars:郑起)

Indexed by:

Scopus SCIE PKU CSCD

Abstract:

A series of Au/CeO2-RE2O3 (RE = Nd, Eu, Sm, Y) catalysts and Au/CeO2-Y2O3 catalysts with different Y2O3 contents were prepared by a deposition-precipitation method. The as-prepared catalysts were investigated by N-2 adsorption-desorption, X-ray diffraction, H-2 temperature-programmed reduction, and Raman spectroscopy, and the catalytic performance was evaluated using water-gas shift (WGS) reaction. The results showed that the catalyst activity and stability are obviously enhanced with the addition of Y2O3, and the best one was found to be the sample with Ce/Y molar ratio equal to 35. This catalyst shows the highest structural stability and a large amount of surface oxygen vacancies, and the interaction between gold and the support is also greatly enhanced.

Keyword:

ceria gold rare earth oxide stability supported catalyst water-gas shift reaction yttria

Community:

  • [ 1 ] [Yang Shenyong]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Zhan Yingying]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Chen Chongqi]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Cao Yanning]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Lin Xingyi]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Zheng Qi]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address:

  • 杨申永

    [Yang Shenyong]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China

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Source :

CHINESE JOURNAL OF CATALYSIS

ISSN: 0253-9837

CN: 21-1601/O6

Year: 2009

Issue: 7

Volume: 30

Page: 666-672

0 . 7 8 6

JCR@2009

1 5 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:3

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 5

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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