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author:

Jiang Li-Long (Jiang Li-Long.) [1] (Scholars:江莉龙) | Ma Yong-De (Ma Yong-De.) [2] (Scholars:马永德) | Cao Yan-Ning (Cao Yan-Ning.) [3] (Scholars:曹彦宁) | Yang Yang (Yang Yang.) [4] | Wei Ke-Mei (Wei Ke-Mei.) [5]

Indexed by:

Scopus SCIE PKU CSCD

Abstract:

Hydrothermally treated bauxite with high surface area was used as a ruthenium-based catalyst support. A series of Ru/bauxite and 2.0% (mass fraction) Ru/Al2O3 catalysts were prepared by incipient-wetness impregnation. The loading content of ruthenium in the Ru/bauxite catalysts was varied from 1.0% to 4.0%. The catalysts were thoroughly characterized by X-ray fluorescence (XRF), low temperature N-2 physical adsorption, X-ray diffraction (XRD), H-2 temperature-programmed reduction (H-2-TPR), and CO temperature-programmed desorption (CO-TPD). The performances of the catalysts for the water-gas shift reaction were also investigated. The results indicated that Ru/bauxite catalysts possess an excellent ability to evolve hydrogen in the water-gas shift reaction. This was attributed to the interaction between Ru and Fe2O3 in the modified bauxite, which could decrease the reduction temperature of Fe2O3, and also improve the adsorption-desorption behavior and decrease the desorption temperature of Ru/bauxite catalysts for CO molecules, resulting in higher activity in the water-gas shift reaction.

Keyword:

Bauxite Hydrogen evolution Ru/bauxite catalyst Water-gas shift

Community:

  • [ 1 ] [Jiang Li-Long]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 2 ] [Ma Yong-De]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 3 ] [Cao Yan-Ning]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 4 ] [Yang Yang]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 5 ] [Wei Ke-Mei]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 江莉龙

    [Jiang Li-Long]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China

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Source :

ACTA PHYSICO-CHIMICA SINICA

ISSN: 1000-6818

CN: 11-1892/O6

Year: 2012

Issue: 3

Volume: 28

Page: 674-680

0 . 8 6 9

JCR@2012

1 0 . 8 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 2

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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