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Abstract:
Hydrothermally treated bauxite with high surface area was used as a ruthenium-based catalyst support. A series of Ru/bauxite and 2.0% (mass fraction) Ru/Al2O3 catalysts were prepared by incipient-wetness impregnation. The loading content of ruthenium in the Ru/bauxite catalysts was varied from 1.0% to 4.0%. The catalysts were thoroughly characterized by X-ray fluorescence (XRF), low temperature N-2 physical adsorption, X-ray diffraction (XRD), H-2 temperature-programmed reduction (H-2-TPR), and CO temperature-programmed desorption (CO-TPD). The performances of the catalysts for the water-gas shift reaction were also investigated. The results indicated that Ru/bauxite catalysts possess an excellent ability to evolve hydrogen in the water-gas shift reaction. This was attributed to the interaction between Ru and Fe2O3 in the modified bauxite, which could decrease the reduction temperature of Fe2O3, and also improve the adsorption-desorption behavior and decrease the desorption temperature of Ru/bauxite catalysts for CO molecules, resulting in higher activity in the water-gas shift reaction.
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ACTA PHYSICO-CHIMICA SINICA
ISSN: 1000-6818
CN: 11-1892/O6
Year: 2012
Issue: 3
Volume: 28
Page: 674-680
0 . 8 6 9
JCR@2012
1 0 . 8 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
JCR Journal Grade:4
CAS Journal Grade:4
Cited Count:
WoS CC Cited Count: 2
SCOPUS Cited Count: 2
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 3
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