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A series of Ag/bauxite catalysts were applied in H-2-promoted selective catalytic reduction (SCR) of NOx. In comparison with 3Ag/Al2O3, 3Ag/bauxite exhibits higher catalytic activity at low temperature, stronger resistance to SO2 poisoning and better regenerability in SCR of NOx. NOx conversion of 3Ag/bauxite at 100-200 degrees C is more than 60%, which is much higher than less than 7% in 3Ag/Al2O3. NH3-TPD and in situ DRIFTS studies confirm the presence of Lewis and Bronsted acid sites in Ag/bauxite, and Lewis acid sites are the major acid sites. H-2-TPR, UV-vis, in situ DRIFTS and DFT calculation show that FeOx and metallic Ag clusters are main active species in SCR of NOx at low temperature. (C) 2014 Elsevier B.V. All rights reserved.
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APPLIED CATALYSIS B-ENVIRONMENTAL
ISSN: 0926-3373
Year: 2015
Volume: 165
Page: 700-705
8 . 3 2 8
JCR@2015
2 0 . 3 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:265
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 29
SCOPUS Cited Count: 31
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 0
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