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author:

Geng, Qiang (Geng, Qiang.) [1] | Lin, Xiahui (Lin, Xiahui.) [2] | Si, Ruiru (Si, Ruiru.) [3] | Chen, Xun (Chen, Xun.) [4] (Scholars:陈旬) | Dai, Wenxin (Dai, Wenxin.) [5] (Scholars:戴文新) | Fu, Xianzhi (Fu, Xianzhi.) [6] (Scholars:付贤智) | Wang, Xuxu (Wang, Xuxu.) [7] (Scholars:王绪绪)

Indexed by:

EI Scopus SCIE

Abstract:

The anatase and rutile TiO2 film sensors were prepared by drop-coating method with calcination at 450 and 600 degrees C, respectively. After tested the ethylene sensing property over the as-prepared TiO2 sensors under UV irradiation, it was found that the anatase TiO2 as well as the rutile sensor exhibited a response to ethylene in the dry nitrogen atmosphere, but with anatase showing a much lower response to ethylene (almost no response) than rutile in the dry air atmosphere (containing oxygen). Moreover, this difference to the ethylene response between the anatase TiO2 sensor and the rutile one was also observed in a wet air atmosphere under UV irradiation. Based on the results of photocatalytically oxidizing ethylene over anatase and rutile TiO2, it is proposed that the weak gas response to ethylene over the anatase TiO2 under UV irradiation can be attributed to the oxidation of ethylene itself. This also suggests that a good photo-assisted semi-conductor sensor should have a strong photoresponse property but a weak photocatalytic performance for the sensed gas. (C) 2012 Elsevier B.V. All rights reserved.

Keyword:

Electron transfer Ethylene response Photocatalytic oxidation Sensor TiO2

Community:

  • [ 1 ] [Geng, Qiang]Fuzhou Univ, State Key Lab Breeding Base, Fujian Prov Key Lab Photocatalysis, Res Inst Photocatalysis, Fuzhou 350002, Peoples R China
  • [ 2 ] [Lin, Xiahui]Fuzhou Univ, State Key Lab Breeding Base, Fujian Prov Key Lab Photocatalysis, Res Inst Photocatalysis, Fuzhou 350002, Peoples R China
  • [ 3 ] [Si, Ruiru]Fuzhou Univ, State Key Lab Breeding Base, Fujian Prov Key Lab Photocatalysis, Res Inst Photocatalysis, Fuzhou 350002, Peoples R China
  • [ 4 ] [Chen, Xun]Fuzhou Univ, State Key Lab Breeding Base, Fujian Prov Key Lab Photocatalysis, Res Inst Photocatalysis, Fuzhou 350002, Peoples R China
  • [ 5 ] [Dai, Wenxin]Fuzhou Univ, State Key Lab Breeding Base, Fujian Prov Key Lab Photocatalysis, Res Inst Photocatalysis, Fuzhou 350002, Peoples R China
  • [ 6 ] [Fu, Xianzhi]Fuzhou Univ, State Key Lab Breeding Base, Fujian Prov Key Lab Photocatalysis, Res Inst Photocatalysis, Fuzhou 350002, Peoples R China
  • [ 7 ] [Wang, Xuxu]Fuzhou Univ, State Key Lab Breeding Base, Fujian Prov Key Lab Photocatalysis, Res Inst Photocatalysis, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 戴文新

    [Dai, Wenxin]Fuzhou Univ, State Key Lab Breeding Base, Fujian Prov Key Lab Photocatalysis, Res Inst Photocatalysis, Fuzhou 350002, Peoples R China

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Source :

SENSORS AND ACTUATORS B-CHEMICAL

ISSN: 0925-4005

Year: 2012

Volume: 174

Page: 449-457

3 . 5 3 5

JCR@2012

8 . 0 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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