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The anatase and rutile TiO 2 film sensors were prepared by drop-coating method with calcination at 450 and 600 °C, respectively. After tested the ethylene sensing property over the as-prepared TiO 2 sensors under UV irradiation, it was found that the anatase TiO 2 as well as the rutile sensor exhibited a response to ethylene in the dry nitrogen atmosphere, but with anatase showing a much lower response to ethylene (almost no response) than rutile in the dry air atmosphere (containing oxygen). Moreover, this difference to the ethylene response between the anatase TiO 2 sensor and the rutile one was also observed in a wet air atmosphere under UV irradiation. Based on the results of photocatalytically oxidizing ethylene over anatase and rutile TiO 2, it is proposed that the weak gas response to ethylene over the anatase TiO 2 under UV irradiation can be attributed to the oxidation of ethylene itself. This also suggests that a good photo-assisted semi-conductor sensor should have a strong photoresponse property but a weak photocatalytic performance for the sensed gas. © 2012 Elsevier B.V.
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Sensors and Actuators, B: Chemical
ISSN: 0925-4005
Year: 2012
Volume: 174
Page: 449-457
3 . 5 3 5
JCR@2012
6 . 3 9 3
JCR@2018
JCR Journal Grade:1
CAS Journal Grade:1
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