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author:

Geng, Q. (Geng, Q..) [1] | Lin, X. (Lin, X..) [2] | Si, R. (Si, R..) [3] | Chen, X. (Chen, X..) [4] | Dai, W. (Dai, W..) [5] | Fu, X. (Fu, X..) [6] | Wang, X. (Wang, X..) [7]

Indexed by:

Scopus

Abstract:

The anatase and rutile TiO 2 film sensors were prepared by drop-coating method with calcination at 450 and 600 °C, respectively. After tested the ethylene sensing property over the as-prepared TiO 2 sensors under UV irradiation, it was found that the anatase TiO 2 as well as the rutile sensor exhibited a response to ethylene in the dry nitrogen atmosphere, but with anatase showing a much lower response to ethylene (almost no response) than rutile in the dry air atmosphere (containing oxygen). Moreover, this difference to the ethylene response between the anatase TiO 2 sensor and the rutile one was also observed in a wet air atmosphere under UV irradiation. Based on the results of photocatalytically oxidizing ethylene over anatase and rutile TiO 2, it is proposed that the weak gas response to ethylene over the anatase TiO 2 under UV irradiation can be attributed to the oxidation of ethylene itself. This also suggests that a good photo-assisted semi-conductor sensor should have a strong photoresponse property but a weak photocatalytic performance for the sensed gas. © 2012 Elsevier B.V.

Keyword:

Electron transfer; Ethylene response; Photocatalytic oxidation; Sensor; TiO 2

Community:

  • [ 1 ] [Geng, Q.]Research Institute of Photocatalysis, Fujian Provincial Key Laboratory of Photocatalysis, Fuzhou University, Fuzhou 350002, China
  • [ 2 ] [Lin, X.]Research Institute of Photocatalysis, Fujian Provincial Key Laboratory of Photocatalysis, Fuzhou University, Fuzhou 350002, China
  • [ 3 ] [Si, R.]Research Institute of Photocatalysis, Fujian Provincial Key Laboratory of Photocatalysis, Fuzhou University, Fuzhou 350002, China
  • [ 4 ] [Chen, X.]Research Institute of Photocatalysis, Fujian Provincial Key Laboratory of Photocatalysis, Fuzhou University, Fuzhou 350002, China
  • [ 5 ] [Dai, W.]Research Institute of Photocatalysis, Fujian Provincial Key Laboratory of Photocatalysis, Fuzhou University, Fuzhou 350002, China
  • [ 6 ] [Fu, X.]Research Institute of Photocatalysis, Fujian Provincial Key Laboratory of Photocatalysis, Fuzhou University, Fuzhou 350002, China
  • [ 7 ] [Wang, X.]Research Institute of Photocatalysis, Fujian Provincial Key Laboratory of Photocatalysis, Fuzhou University, Fuzhou 350002, China

Reprint 's Address:

  • [Dai, W.]Research Institute of Photocatalysis, Fujian Provincial Key Laboratory of Photocatalysis, Fuzhou University, Fuzhou 350002, China

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Source :

Sensors and Actuators, B: Chemical

ISSN: 0925-4005

Year: 2012

Volume: 174

Page: 449-457

3 . 5 3 5

JCR@2012

6 . 3 9 3

JCR@2018

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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