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author:

Lin Chun-xiang (Lin Chun-xiang.) [1] (Scholars:林春香) | Zhan Huai-yu (Zhan Huai-yu.) [2] | Liu Ming-hua (Liu Ming-hua.) [3] | Fu Shi-yu (Fu Shi-yu.) [4] | Lucia, Lucian (Lucia, Lucian.) [5]

Indexed by:

Scopus SCIE CSCD

Abstract:

The kinetics of atom transfer radical polymerization(ATRP) of methyl methacrylate(MMA) initiated by cellulose based macroinitator, cellulose chloroacetate, performed in ionic liquid(1-N-butyl-3-methylimidazolium chloride, BMIMCl), dimethyl sulfoxide(DMSO) and dimethyl formamide(DMF) were respectively studied in detail. The polymerizations were carried out under homogeneous conditions with CuBr as catalyst and 2,2'-bipyridine(bpy) as ligand. The dependences of the rate of polymerization on solvent, temperature, monomer/initiator ratio and catalyst/ligand ratio were presented. Plots of ln([M](0)/[M](t)) vs. time and molecular weight vs. conversion showed a linear dependence, indicating a constant number of propagating species throughout the polymerization as well as a negligible contribution of termination or transfer reactions. On the basis of an Arrhenius plot, the apparent energy of activation(Delta E-a(aPP)) for ATRP of MMA in BMIMCl was 16.6 kJ/mol which is much lower than that in diphenyl ether.

Keyword:

Atom transfer radical polymerization(ATRP) Kinetics Methyl methacrylate

Community:

  • [ 1 ] [Lin Chun-xiang]Fuzhou Univ, Coll Environm & Resources, Fuzhou 350002, Peoples R China
  • [ 2 ] [Liu Ming-hua]Fuzhou Univ, Coll Environm & Resources, Fuzhou 350002, Peoples R China
  • [ 3 ] [Zhan Huai-yu]S China Univ Technol, State Key Lab Pulp & Paper Engn, Guangzhou 510640, Guangdong, Peoples R China
  • [ 4 ] [Fu Shi-yu]S China Univ Technol, State Key Lab Pulp & Paper Engn, Guangzhou 510640, Guangdong, Peoples R China
  • [ 5 ] [Lucia, Lucian]S China Univ Technol, State Key Lab Pulp & Paper Engn, Guangzhou 510640, Guangdong, Peoples R China
  • [ 6 ] [Lucia, Lucian]N Carolina State Univ, Dept Wood & Paper Sci, Lab Soft Mat & Green Chem, Raleigh, NC 27695 USA

Reprint 's Address:

  • 刘明华

    [Liu Ming-hua]Fuzhou Univ, Coll Environm & Resources, Fuzhou 350002, Peoples R China

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Source :

CHEMICAL RESEARCH IN CHINESE UNIVERSITIES

ISSN: 1005-9040

CN: 22-1183/O6

Year: 2013

Issue: 1

Volume: 29

Page: 159-165

1 . 1 1 9

JCR@2013

3 . 1 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:3

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 4

SCOPUS Cited Count: 4

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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