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Abstract:
The kinetics of atom transfer radical polymerization(ATRP) of methyl methacrylate(MMA) initiated by cellulose based macroinitator, cellulose chloroacetate, performed in ionic liquid(1-N-butyl-3-methylimidazolium chloride, BMIMCl), dimethyl sulfoxide(DMSO) and dimethyl formamide(DMF) were respectively studied in detail. The polymerizations were carried out under homogeneous conditions with CuBr as catalyst and 2,2'-bipyridine(bpy) as ligand. The dependences of the rate of polymerization on solvent, temperature, monomer/initiator ratio and catalyst/ligand ratio were presented. Plots of ln([M](0)/[M](t)) vs. time and molecular weight vs. conversion showed a linear dependence, indicating a constant number of propagating species throughout the polymerization as well as a negligible contribution of termination or transfer reactions. On the basis of an Arrhenius plot, the apparent energy of activation(Delta E-a(aPP)) for ATRP of MMA in BMIMCl was 16.6 kJ/mol which is much lower than that in diphenyl ether.
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CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
ISSN: 1005-9040
CN: 22-1183/O6
Year: 2013
Issue: 1
Volume: 29
Page: 159-165
1 . 1 1 9
JCR@2013
3 . 1 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
JCR Journal Grade:3
CAS Journal Grade:4
Cited Count:
WoS CC Cited Count: 4
SCOPUS Cited Count: 4
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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