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The study of polymerization in methyl methacrylate (MMA)/acrylic acid (AA) oil-in-water microemulsions stabilized by sodium dodecyl sulfate and OP emulsifier was carried out by using dilatometry with potassium permanganate as initiator. The influence of initiator type, reaction temperature, the concentration of initiator or monomer and the mass ratio of AA to MMA on the monomer conversion and the rate of polymerization was investigated. The results showed that the monomer conversion and the rate of polymerization using potassium permanganate as initiator was similar to that using potassium persulphate but much higher than that using 2.2′-azobisisobutyronitrile. Keeping the constant composition of microemulsion, the rate of polymerization and final conversion increased first and then dropped with increasing temperature, and the total apparent active energy was -82.7 kJ/mol above 35°C. The rate of polymerization and final conversion increased and reached maximum with increasing the concentration of potassium permanganate. And peak polymerization rate and maximal final conversion appeared with increasing the concentration of monomer or the ratio of AA to MMA. In addition, the period of constant rate during polymerization was observed at appropriate conditions.
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Journal of Basic Science and Engineering
ISSN: 1005-0930
CN: 11-3242/TB
Year: 2005
Issue: 3
Volume: 13
Page: 247-253
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 4
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