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Abstract:
The kinetics of acrylates copolymerization initiated with azobisisobutyronitrile (AIBN) in inverse microemulsions composed of methyl methacrylate (MMA) -butyl acrylate (BA)/dodecyl sodium sulfate (SDS) -acrylic acid (AA)/water was studied. The results showed that the apparent polymerization rate at 5% conversion increased with increased AIBN concentration, AA concentration, aqueous fraction and reaction temperature while decreased with increased SDS concentration, and the kinetic relation was obtained. Nucleation in aqueous droplet was considered to be important. Furthermore, the total apparent activation energy was found to be 114 kJ·mol-1.
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Journal of Chemical Industry and Engineering (China)
ISSN: 0438-1157
CN: 11-1946/TQ
Year: 2004
Issue: 7
Volume: 55
Page: 1168-1172
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 2
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