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author:

Li, Xiao (Li, Xiao.) [1] (Scholars:李晓) | Gao, Jing (Gao, Jing.) [2] | Zhang, Weiying (Zhang, Weiying.) [3] (Scholars:张卫英) | Zeng, Weijie (Zeng, Weijie.) [4]

Indexed by:

EI Scopus PKU CSCD

Abstract:

The kinetics of acrylates copolymerization initiated with azobisisobutyronitrile (AIBN) in inverse microemulsions composed of methyl methacrylate (MMA) -butyl acrylate (BA)/dodecyl sodium sulfate (SDS) -acrylic acid (AA)/water was studied. The results showed that the apparent polymerization rate at 5% conversion increased with increased AIBN concentration, AA concentration, aqueous fraction and reaction temperature while decreased with increased SDS concentration, and the kinetic relation was obtained. Nucleation in aqueous droplet was considered to be important. Furthermore, the total apparent activation energy was found to be 114 kJ·mol-1.

Keyword:

Acrylics Activation energy Copolymerization Initiators (chemical) Microemulsions Nucleation Reaction kinetics

Community:

  • [ 1 ] [Li, Xiao]Sch. of Chem. and Chem. Eng., Fuzhou Univ., Fuzhou 350002, China
  • [ 2 ] [Gao, Jing]Sch. of Chem. and Chem. Eng., Fuzhou Univ., Fuzhou 350002, China
  • [ 3 ] [Zhang, Weiying]Sch. of Chem. and Chem. Eng., Fuzhou Univ., Fuzhou 350002, China
  • [ 4 ] [Zeng, Weijie]Sch. of Chem. and Chem. Eng., Fuzhou Univ., Fuzhou 350002, China

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Source :

Journal of Chemical Industry and Engineering (China)

ISSN: 0438-1157

CN: 11-1946/TQ

Year: 2004

Issue: 7

Volume: 55

Page: 1168-1172

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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