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[期刊论文]

Synthesis, Magnetism, and Thermostability of a Series of Two-Dimensional LanthanideNickel Heterometallic Coordination Polymers

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author:

Chen, Wen-Xian (Chen, Wen-Xian.) [1] | Zhuang, Gui-Lin (Zhuang, Gui-Lin.) [2] | Wu, Shu-Ting (Wu, Shu-Ting.) [3] (Scholars:吴舒婷)

Indexed by:

Scopus SCIE

Abstract:

A series of LnNi heterometallic coordination polymers, {[Ln2Ni(MIDA)4(H2O)6](H2O)4} (Ln = La (1), Ce (2), Pr (3), and Nd (4); H2MIDA = N-methyl-iminodiacetic acid), were obtained under hydrothermal conditions. Single crystal X-ray diffraction revealed that they feature two-dimensional isomorphic frameworks, which could be viewed as the construction by one-dimensional {Ln}n chain connecting by bridges of [Ni(MIDA)2]2. The magnetic measurements reveal that compounds 24 exhibit antiferromagnetic properties. TGA results indicate compounds 1 and 4 have good thermostability with the critical temperature of 375 degrees C.

Keyword:

Heterometallic coordination polymers Lanthanide contraction Lanthanides Magnetic properties Thermostability

Community:

  • [ 1 ] [Chen, Wen-Xian]Zhejiang Univ Technol, Coll Chem Engn & Mat Sci, Hangzhou, Zhejiang, Peoples R China
  • [ 2 ] [Zhuang, Gui-Lin]Zhejiang Univ Technol, Coll Chem Engn & Mat Sci, Hangzhou, Zhejiang, Peoples R China
  • [ 3 ] [Wu, Shu-Ting]Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • [Zhuang, Gui-Lin]Zhejiang Univ Technol, Coll Chem Engn & Mat Sci, Hangzhou, Zhejiang, Peoples R China

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Source :

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

ISSN: 0044-2313

Year: 2013

Issue: 5

Volume: 639

Page: 817-820

1 . 2 5 1

JCR@2013

1 . 1 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 4

SCOPUS Cited Count: 3

30 Days PV: 1

Online/Total:149/10201880
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