Studies on Photocatalytic CO2 Reduction over NH2-Uio-66(Zr) and Its Derivatives: Towards a Better Understanding of Photocatalysis on Metal-Organic Frameworks - Details

author：

Indexed by：

EI Scopus SCIE

Abstract：

Metal-organic　framework　(MOF)　NH2-Uio-66(Zr)　exhibits　photocatalytic　activity　for　CO2　reduction　in　the　presence　of　triethanolamine　as　sacrificial　agent　under　visible-light　irradiation.　Photoinduced　electron　transfer　from　the　excited　2-aminoterephthalate　(ATA)　to　Zr　oxo　clusters　in　NH2-Uio-66(Zr)　was　for　the　first　time　revealed　by　photoluminescence　studies.　Generation　of　Zr-III　and　its　involvement　in　photocatalytic　CO2　reduction　was　confirmed　by　ESR　analysis.　Moreover,　NH2-Uio-66(Zr)　with　mixed　ATA　and　2,5-diaminoterephthalate　(DTA)　ligands　was　prepared　and　shown　to　exhibit　higher　performance　for　photocatalytic　CO2　reduction　due　to　its　enhanced　light　adsorption　and　increased　adsorption　of　CO2.　This　study　provides　a　better　understanding　of　photocatalytic　CO2　reduction　over　MOF-based　photocatalysts　and　also　demonstrates　the　great　potential　of　using　MOFs　as　highly　stable,　molecularly　tunable,　and　recyclable　photocatalysts　in　CO2　reduction.

Keyword：

carbon dioxide fixation metal-organic frameworks photochemistry reduction zirconium

Community：

[ 1 ] [Sun, Dengrong]Fuzhou Univ, Res Inst Photocatalysis, Fujian Prov Key Lab Photocatalysis, State Key Lab Breeding Base,Coll Chem & Chem Engn, Fuzhou 350002, Peoples R China
[ 2 ] [Fu, Yanghe]Fuzhou Univ, Res Inst Photocatalysis, Fujian Prov Key Lab Photocatalysis, State Key Lab Breeding Base,Coll Chem & Chem Engn, Fuzhou 350002, Peoples R China
[ 3 ] [Liu, Wenjun]Fuzhou Univ, Res Inst Photocatalysis, Fujian Prov Key Lab Photocatalysis, State Key Lab Breeding Base,Coll Chem & Chem Engn, Fuzhou 350002, Peoples R China
[ 4 ] [Ye, Lin]Fuzhou Univ, Res Inst Photocatalysis, Fujian Prov Key Lab Photocatalysis, State Key Lab Breeding Base,Coll Chem & Chem Engn, Fuzhou 350002, Peoples R China
[ 5 ] [Wang, Dengke]Fuzhou Univ, Res Inst Photocatalysis, Fujian Prov Key Lab Photocatalysis, State Key Lab Breeding Base,Coll Chem & Chem Engn, Fuzhou 350002, Peoples R China
[ 6 ] [Yang, Lin]Fuzhou Univ, Res Inst Photocatalysis, Fujian Prov Key Lab Photocatalysis, State Key Lab Breeding Base,Coll Chem & Chem Engn, Fuzhou 350002, Peoples R China
[ 7 ] [Fu, Xianzhi]Fuzhou Univ, Res Inst Photocatalysis, Fujian Prov Key Lab Photocatalysis, State Key Lab Breeding Base,Coll Chem & Chem Engn, Fuzhou 350002, Peoples R China
[ 8 ] [Li, Zhaohui]Fuzhou Univ, Res Inst Photocatalysis, Fujian Prov Key Lab Photocatalysis, State Key Lab Breeding Base,Coll Chem & Chem Engn, Fuzhou 350002, Peoples R China

Reprint 's Address：

李朝晖
[Li, Zhaohui]Fuzhou Univ, Res Inst Photocatalysis, Fujian Prov Key Lab Photocatalysis, State Key Lab Breeding Base,Coll Chem & Chem Engn, Fuzhou 350002, Peoples R China

Email：

zhaohuili1969@yahoo.com

Show more details

Version：