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author:

Hou, Keyu (Hou, Keyu.) [1] | Huang, Lei (Huang, Lei.) [2] | Qi, Yongbo (Qi, Yongbo.) [3] | Huang, Caixia (Huang, Caixia.) [4] | Pan, Haibo (Pan, Haibo.) [5] (Scholars:潘海波) | Du, Min (Du, Min.) [6]

Indexed by:

EI Scopus SCIE

Abstract:

In this work, a novel zinc phthalocyanine tetrasulfonic acid (ZnTsPc)-fiinctionalized graphene nanocomposites (f-GN) was synthesized by a simple and efficient electrostatic self-assembly method, where the positive charged GN decorated by (3-aminopropyl) triethoxysilane (APES) was self-assemblied with ZnTsPc, a two dimensional (2-D) molecules. It not only enhanced its stability for the hybrid structure, but also avoided the reaggregation of ZnTsPc or f-GN themselves. Based on layered ZnTsPc/f-GN nanocomposites modified glassy carbon electrode, a rapid and sensitive sensor was developed for the determination of bisphenol A (BPA). Under the optimal conditions, the oxidation peak current increased linearly with the concentration of BPA in the range of 5.0 x 10(-8) to 4.0 x 10(-8) M with correlation coefficient 0.998 and limits of detection 2.0 x 10(-8) M. Due to high absorption nature for BPA and electron deficiency on ZnTsPc/f-GN, it presented the unique electron pathway arising from pi-pi stackable interaction during redox process for detecting BPA. The sensor exhibited remarkable long-term stability, good anti-interference and excellent electrocatalytic activity towards BPA detection. (C) 2015 Elsevier B.V. All rights reserved.

Keyword:

Bisphenol A detection Graphene Metallophthalocyanine pi-pi stack Self-assembly

Community:

  • [ 1 ] [Hou, Keyu]Fuzhou Univ, Fujian Key Lab Med Instrument & Pharmaceut Techno, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Huang, Caixia]Fuzhou Univ, Fujian Key Lab Med Instrument & Pharmaceut Techno, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Pan, Haibo]Fuzhou Univ, Fujian Key Lab Med Instrument & Pharmaceut Techno, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Du, Min]Fuzhou Univ, Fujian Key Lab Med Instrument & Pharmaceut Techno, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Hou, Keyu]Fuzhou Univ, Inst Res Funct Mat, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Huang, Lei]Fuzhou Univ, Inst Res Funct Mat, Fuzhou 350002, Fujian, Peoples R China
  • [ 7 ] [Qi, Yongbo]Fuzhou Univ, Inst Res Funct Mat, Fuzhou 350002, Fujian, Peoples R China
  • [ 8 ] [Huang, Caixia]Fuzhou Univ, Inst Res Funct Mat, Fuzhou 350002, Fujian, Peoples R China
  • [ 9 ] [Pan, Haibo]Fuzhou Univ, Inst Res Funct Mat, Fuzhou 350002, Fujian, Peoples R China
  • [ 10 ] [Hou, Keyu]Fuzhou Univ, Coll Chem, Fujian 3501196, Fujian, Peoples R China
  • [ 11 ] [Huang, Lei]Fuzhou Univ, Coll Chem, Fujian 3501196, Fujian, Peoples R China
  • [ 12 ] [Qi, Yongbo]Fuzhou Univ, Coll Chem, Fujian 3501196, Fujian, Peoples R China
  • [ 13 ] [Huang, Caixia]Fuzhou Univ, Coll Chem, Fujian 3501196, Fujian, Peoples R China
  • [ 14 ] [Pan, Haibo]Fuzhou Univ, Coll Chem, Fujian 3501196, Fujian, Peoples R China

Reprint 's Address:

  • 潘海波

    [Pan, Haibo]Fuzhou Univ, Fujian Key Lab Med Instrument & Pharmaceut Techno, Yishan Campus, Fuzhou 350002, Fujian, Peoples R China

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Source :

MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS

ISSN: 0928-4931

Year: 2015

Volume: 49

Page: 640-647

3 . 4 2

JCR@2015

8 . 1 0 0

JCR@2023

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 26

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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