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author:

Hou, Keyu (Hou, Keyu.) [1] | Huang, Lei (Huang, Lei.) [2] | Qi, Yongbo (Qi, Yongbo.) [3] | Huang, Caixia (Huang, Caixia.) [4] | Pan, Haibo (Pan, Haibo.) [5] | Du, Min (Du, Min.) [6]

Indexed by:

EI

Abstract:

In this work, a novel zinc phthalocyanine tetrasulfonic acid (ZnTsPc)-functionalized graphene nanocomposites (f-GN) was synthesized by a simple and efficient electrostatic self-assembly method, where the positive charged GN decorated by (3-aminopropyl) triethoxysilane (APTES) was self-assemblied with ZnTsPc, a two dimensional (2-D) molecules. It not only enhanced its stability for the hybrid structure, but also avoided the reaggregation of ZnTsPc or f-GN themselves. Based on layered ZnTsPc/f-GN nanocomposites modified glassy carbon electrode, a rapid and sensitive sensor was developed for the determination of bisphenol A (BPA). Under the optimal conditions, the oxidation peak current increased linearly with the concentration of BPA in the range of 5.0 × 10- 8 to 4.0 × 10- 6 M with correlation coefficient 0.998 and limits of detection 2.0 × 10- 8 M. Due to high absorption nature for BPA and electron deficiency on ZnTsPc/f-GN, it presented the unique electron pathway arising from π-π stackable interaction during redox process for detecting BPA. The sensor exhibited remarkable long-term stability, good anti-interference and excellent electrocatalytic activity towards BPA detection. © 2015 Elsevier B.V.

Keyword:

Glass membrane electrodes Graphene Nanocomposites Phenols Self assembly Synthesis (chemical) Zinc Zinc compounds

Community:

  • [ 1 ] [Hou, Keyu]Fujian Key Lab of Medical Instrument and Pharmaceutical Technology, Yishan Campus, Fuzhou University, Fuzhou, Fujian; 350002, China
  • [ 2 ] [Hou, Keyu]Institute of Research for Functional Materials, Yishan Campus, Fuzhou University, Fuzhou, Fujian; 350002, China
  • [ 3 ] [Hou, Keyu]College of Chemistry, Qishan Campus, Fuzhou University, Fuzhou, Fujian; 350116, China
  • [ 4 ] [Huang, Lei]Institute of Research for Functional Materials, Yishan Campus, Fuzhou University, Fuzhou, Fujian; 350002, China
  • [ 5 ] [Huang, Lei]College of Chemistry, Qishan Campus, Fuzhou University, Fuzhou, Fujian; 350116, China
  • [ 6 ] [Qi, Yongbo]Institute of Research for Functional Materials, Yishan Campus, Fuzhou University, Fuzhou, Fujian; 350002, China
  • [ 7 ] [Qi, Yongbo]College of Chemistry, Qishan Campus, Fuzhou University, Fuzhou, Fujian; 350116, China
  • [ 8 ] [Huang, Caixia]Fujian Key Lab of Medical Instrument and Pharmaceutical Technology, Yishan Campus, Fuzhou University, Fuzhou, Fujian; 350002, China
  • [ 9 ] [Huang, Caixia]Institute of Research for Functional Materials, Yishan Campus, Fuzhou University, Fuzhou, Fujian; 350002, China
  • [ 10 ] [Huang, Caixia]College of Chemistry, Qishan Campus, Fuzhou University, Fuzhou, Fujian; 350116, China
  • [ 11 ] [Pan, Haibo]Fujian Key Lab of Medical Instrument and Pharmaceutical Technology, Yishan Campus, Fuzhou University, Fuzhou, Fujian; 350002, China
  • [ 12 ] [Pan, Haibo]Institute of Research for Functional Materials, Yishan Campus, Fuzhou University, Fuzhou, Fujian; 350002, China
  • [ 13 ] [Pan, Haibo]College of Chemistry, Qishan Campus, Fuzhou University, Fuzhou, Fujian; 350116, China
  • [ 14 ] [Du, Min]Fujian Key Lab of Medical Instrument and Pharmaceutical Technology, Yishan Campus, Fuzhou University, Fuzhou, Fujian; 350002, China

Reprint 's Address:

  • [pan, haibo]fujian key lab of medical instrument and pharmaceutical technology, yishan campus, fuzhou university, fuzhou, fujian; 350002, china;;[pan, haibo]college of chemistry, qishan campus, fuzhou university, fuzhou, fujian; 350116, china;;[pan, haibo]institute of research for functional materials, yishan campus, fuzhou university, fuzhou, fujian; 350002, china

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Source :

Materials Science and Engineering C

ISSN: 0928-4931

Year: 2015

Volume: 49

Page: 640-647

3 . 4 2

JCR@2015

8 . 1 0 0

JCR@2023

JCR Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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