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In this work, a novel zinc phthalocyanine tetrasulfonic acid (ZnTsPc)-functionalized graphene nanocomposites (f-GN) was synthesized by a simple and efficient electrostatic self-assembly method, where the positive charged GN decorated by (3-aminopropyl) triethoxysilane (APTES) was self-assemblied with ZnTsPc, a two dimensional (2-D) molecules. It not only enhanced its stability for the hybrid structure, but also avoided the reaggregation of ZnTsPc or f-GN themselves. Based on layered ZnTsPc/f-GN nanocomposites modified glassy carbon electrode, a rapid and sensitive sensor was developed for the determination of bisphenol A (BPA). Under the optimal conditions, the oxidation peak current increased linearly with the concentration of BPA in the range of 5.0 × 10- 8 to 4.0 × 10- 6 M with correlation coefficient 0.998 and limits of detection 2.0 × 10- 8 M. Due to high absorption nature for BPA and electron deficiency on ZnTsPc/f-GN, it presented the unique electron pathway arising from π-π stackable interaction during redox process for detecting BPA. The sensor exhibited remarkable long-term stability, good anti-interference and excellent electrocatalytic activity towards BPA detection. © 2015 Elsevier B.V.
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Materials Science and Engineering C
ISSN: 0928-4931
Year: 2015
Volume: 49
Page: 640-647
3 . 4 2
JCR@2015
8 . 1 0 0
JCR@2023
JCR Journal Grade:2
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 1
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