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author:

Lin, Xingyi (Lin, Xingyi.) [1] (Scholars:林性贻) | Li, Rule (Li, Rule.) [2] | Lu, Miaomiao (Lu, Miaomiao.) [3] | Chen, Chongqi (Chen, Chongqi.) [4] (Scholars:陈崇启) | Li, Dalin (Li, Dalin.) [5] | Zhan, Yingying (Zhan, Yingying.) [6] (Scholars:詹瑛瑛) | Jiang, Lilong (Jiang, Lilong.) [7] (Scholars:江莉龙)

Indexed by:

EI Scopus SCIE

Abstract:

A series of supported Ni/Mg/Al catalysts with Ni loadings of 3-18 wt% were prepared from Ni-Mg-Al layered double hydroxides and tested for the CH4-CO2 reforming. The influence of Ni loading on the catalyst activity and stability was studied. It is found that the catalyst activity increased with increasing the Ni loading. However, the CO disproportionation became significant as the Ni loading increased. The long-term stability of the Ni/Mg/Al catalysts was influenced by the Ni loading as well as the reaction temperature. At a high temperature of 1023 K, the catalyst stability increased with increasing the Ni loading, whereas it decreased with increasing the Ni loading at a low temperature of 873 K. The characterization on the spent Ni/Mg/Al catalysts showed that the sintering of Ni metal particles increased with increasing the Ni loading, and it became more severe at 873 K than at 1023 K. On the other hand, the coke deposition at 1023 K tended to decrease with increasing the Ni loading, and an opposite tendency was observed at 873 K. The coke deposition particularly the encapsulating carbon was considered to be responsible for the catalyst deactivation. A Ni loading of 12 wt% would be suitable for the Ni/Mg/Al catalyst considering its high activity, good stability, and less coke deposition at high temperature. (C) 2015 Elsevier Ltd. All rights reserved.

Keyword:

Carbon dioxide Layered double hydroxides Methane Ni catalyst Synthesis gas

Community:

  • [ 1 ] [Lin, Xingyi]Fuzhou Univ, Sch Chem Engn, NERC CFC, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Li, Rule]Fuzhou Univ, Sch Chem Engn, NERC CFC, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Lu, Miaomiao]Fuzhou Univ, Sch Chem Engn, NERC CFC, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Chen, Chongqi]Fuzhou Univ, Sch Chem Engn, NERC CFC, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Li, Dalin]Fuzhou Univ, Sch Chem Engn, NERC CFC, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Zhan, Yingying]Fuzhou Univ, Sch Chem Engn, NERC CFC, Fuzhou 350002, Fujian, Peoples R China
  • [ 7 ] [Jiang, Lilong]Fuzhou Univ, Sch Chem Engn, NERC CFC, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address:

  • 李达林

    [Li, Dalin]Fuzhou Univ, Sch Chem Engn, NERC CFC, Gongye Rd 523, Fuzhou 350002, Fujian, Peoples R China

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Source :

FUEL

ISSN: 0016-2361

Year: 2015

Volume: 162

Page: 271-280

3 . 6 1 1

JCR@2015

6 . 7 0 0

JCR@2023

ESI Discipline: ENGINEERING;

ESI HC Threshold:183

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 85

SCOPUS Cited Count: 86

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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