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author:

Ye, Changshen (Ye, Changshen.) [1] (Scholars:叶长燊) | Lin, Meihong (Lin, Meihong.) [2] | Qi, Zhaoyang (Qi, Zhaoyang.) [3] | Zhu, Wenjie (Zhu, Wenjie.) [4] | Yang, Chen (Yang, Chen.) [5] (Scholars:杨臣) | Qiu, Ting (Qiu, Ting.) [6] (Scholars:邱挺)

Indexed by:

Scopus SCIE

Abstract:

Removal of Co(II) and Mn(II) ions from the pure terephthalic acid (PTA) wastewater onto Na-bentonite has been investigated in this work. Batch experiments were performed to elucidate the effects of various parameters, such as dosage of adsorbent, temperature, and initial pH, on the adsorption process. It has been found that the simulated adsorption process of the pseudo-second-order kinetic model was in better agreement with experimental results than that of the pseudo-first-order and intra-particle diffusion kinetic models. Moreover, the adsorption experiments were conducted at four temperatures, which was 298.15, 308.15, 318.15, and 328.15K, respectively, with the initial metal concentrations ranging from 30 to 120mgL(-1), so as to study the adsorption thermodynamics. Compared with the Freundlich and Dubinin-Radushkevich models, the Langmuir isotherm model agreed better with experimental data. The Gibb's free energy change (G), enthalpy change (H), and entropy change (S) of the adsorption process were calculated at four temperatures. The results indicated that the adsorption process was endothermic and spontaneous. When the adsorbent concentration was 3gL(-1), the adsorption percentages of Co(II) and Mn(II) can be attained about 95.09 and 95.03%, respectively. Therefore, it can be concluded that Na-bentonite could be used as an efficient adsorbent to remove heavy metal ions from the PTA wastewater.

Keyword:

Adsorption Adsorption isotherm Adsorption mechanism Co(II) and Mn(II) ions Na-bentonite

Community:

  • [ 1 ] [Ye, Changshen]Fuzhou Univ, Sch Chem Engn, Fuzhou 350116, Peoples R China
  • [ 2 ] [Lin, Meihong]Fuzhou Univ, Sch Chem Engn, Fuzhou 350116, Peoples R China
  • [ 3 ] [Qi, Zhaoyang]Fuzhou Univ, Sch Chem Engn, Fuzhou 350116, Peoples R China
  • [ 4 ] [Zhu, Wenjie]Fuzhou Univ, Sch Chem Engn, Fuzhou 350116, Peoples R China
  • [ 5 ] [Yang, Chen]Fuzhou Univ, Sch Chem Engn, Fuzhou 350116, Peoples R China
  • [ 6 ] [Qiu, Ting]Fuzhou Univ, Sch Chem Engn, Fuzhou 350116, Peoples R China

Reprint 's Address:

  • 邱挺

    [Qiu, Ting]Fuzhou Univ, Sch Chem Engn, Fuzhou 350116, Peoples R China

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Source :

DESALINATION AND WATER TREATMENT

ISSN: 1944-3994

Year: 2016

Issue: 44

Volume: 57

Page: 20856-20866

1 . 6 3 1

JCR@2016

1 . 1 0 0

JCR@2022

ESI Discipline: ENGINEERING;

ESI HC Threshold:166

JCR Journal Grade:2

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 2

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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