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Abstract:
Two isostructural metal-organic frameworks formulated as [Gd-7(L)(4)(mu(3)-OH)(8)(HCOO)(DMF)(6)(H2O)]center dot DMF center dot H2O (1) and [Tb-7(L)(4)(mu(3)-OH)(8)(HCOO)(DMF)(5)(H2O)]center dot DMF center dot H2O (2) (H3L=3,5-di(4'-carboxylphenyl)benzoic acid) have been synthesized and structurally characterized. The building blocks of the structures are the heptanuclear lanthanide clusters of the dicubane-like type [Ln(7)(mu(3)-OH)(8)](13+) (Ln=Gd, Tb) which are formally assembled into porous three-dimensional networks through the linkage of L. Variable temperature magnetic studies down to 2 K reveal antiferromagnetic interactions in complex 1. Furthermore, the fluorescence property of 2 was also studied.
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CHINESE JOURNAL OF CHEMISTRY
ISSN: 1001-604X
CN: 31-1547/O6
Year: 2016
Issue: 2
Volume: 34
Page: 210-214
1 . 8 5 2
JCR@2016
5 . 5 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:235
JCR Journal Grade:3
CAS Journal Grade:4
Cited Count:
WoS CC Cited Count: 0
SCOPUS Cited Count: 1
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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