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Abstract:
Two isostructural metal-organic frameworks formulated as [Gd7(L)4(μ3-OH)8(HCOO)(DMF)6(H2O)]·DMF·H2O (1) and [Tb7(L)4(μ3-OH)8(HCOO)(DMF)5(H2O)]·DMF·H2O (2) (H3L=3,5-di(4′-carboxylphenyl)benzoic acid) have been synthesized and structurally characterized. The building blocks of the structures are the heptanuclear lanthanide clusters of the dicubane-like type [Ln7(μ3-OH)8]13+ (Ln=Gd, Tb) which are formally assembled into porous three-dimensional networks through the linkage of L. Variable temperature magnetic studies down to 2 K reveal antiferromagnetic interactions in complex 1. Furthermore, the fluorescence property of 2 was also studied. Two isostructural 3D lanthanide-containing MOFs constructed from an unprecedented [Ln7(μ3-OH)8]13+ (Ln=Gd, Tb) cluster in which the Ln3+ ions are arranged in a distorted vertexsharing dicubane-like geometry were obtained based on a rigid tripodal ligand. Furthermore, the magnetic property of 1 and the fluorescent property of 2 were also studied. Copyright © 2016 SIOC, CAS, Shanghai & WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Chinese Journal of Chemistry
ISSN: 1001-604X
Year: 2016
Issue: 2
Volume: 34
Page: 210-214
1 . 8 5 2
JCR@2016
5 . 5 0 0
JCR@2023
ESI HC Threshold:235
JCR Journal Grade:3
CAS Journal Grade:4
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 3
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