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author:

Liu, L. (Liu, L..) [1] | Shen, C. (Shen, C..) [2] | Dong, F. (Dong, F..) [3] | Wang, W. (Wang, W..) [4] | Yuan, D. (Yuan, D..) [5]

Indexed by:

Scopus CSCD

Abstract:

Two isostructural metal-organic frameworks formulated as [Gd7(L)4(μ3-OH)8(HCOO)(DMF)6(H2O)]·DMF·H2O (1) and [Tb7(L)4(μ3-OH)8(HCOO)(DMF)5(H2O)]·DMF·H2O (2) (H3L=3,5-di(4′-carboxylphenyl)benzoic acid) have been synthesized and structurally characterized. The building blocks of the structures are the heptanuclear lanthanide clusters of the dicubane-like type [Ln7(μ3-OH)8]13+ (Ln=Gd, Tb) which are formally assembled into porous three-dimensional networks through the linkage of L. Variable temperature magnetic studies down to 2 K reveal antiferromagnetic interactions in complex 1. Furthermore, the fluorescence property of 2 was also studied. Two isostructural 3D lanthanide-containing MOFs constructed from an unprecedented [Ln7(μ3-OH)8]13+ (Ln=Gd, Tb) cluster in which the Ln3+ ions are arranged in a distorted vertexsharing dicubane-like geometry were obtained based on a rigid tripodal ligand. Furthermore, the magnetic property of 1 and the fluorescent property of 2 were also studied. Copyright © 2016 SIOC, CAS, Shanghai & WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keyword:

fluorescent; heptanuclear lanthanide cluster; magnetic; MOFs

Community:

  • [ 1 ] [Liu, L.]College of Chemistry, Fuzhou University, Fuzhou, Fujian, 350002, China
  • [ 2 ] [Shen, C.]College of Chemistry, Fuzhou University, Fuzhou, Fujian, 350002, China
  • [ 3 ] [Shen, C.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China
  • [ 4 ] [Dong, F.]College of Chemistry, Fuzhou University, Fuzhou, Fujian, 350002, China
  • [ 5 ] [Wang, W.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China
  • [ 6 ] [Yuan, D.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China

Reprint 's Address:

  • [Shen, C.]College of Chemistry, Fuzhou UniversityChina

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Source :

Chinese Journal of Chemistry

ISSN: 1001-604X

Year: 2016

Issue: 2

Volume: 34

Page: 210-214

1 . 8 5 2

JCR@2016

5 . 5 0 0

JCR@2023

ESI HC Threshold:235

JCR Journal Grade:3

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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