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Abstract:
beta-nucleated long chain branched (LCB) polypropylene random copolymers (PPRs) were prepared via reactive extrusion by introducing beta nucleating agent (NA), dicumyl peroxide (DCP) and various contents of 1, 6-Hexanediol diacrylate (HDDA) into PPR. Results of Fourier infrared spectroscopy (FTIR) and the rheological properties demonstrate the existence of LCB polypropylene. Mechanical properties including impact strength, tensile strength and elongation at break were studied. The crystal structure, morphology and crystallization behavior were investigated via wide-angle X-ray diffraction (WARD), polarized light microscopy (PLM) and differential scanning calorimetry (DSC). Non-isothermal crystallization kinetics using the Jeziorny method was also studied. The results show an increased LCB degree with increasing HDDA amount For the sample with a moderate LCB level, synergistic toughening effect of NA and LCB is achieved without deterioration of yield strength or elongation at break, partially because of its higher beta-phase content and much smaller spherulite size. It exhibits the minimum values of T-c and Z(c1), and the maximum values of t(1/2) and n(1) in the primary stage of crystallization, regardless of the cooling rate, indicating a slower crystallization rate and more complicated nucleation and crystal growth model. (C) 2016 Elsevier Ltd. All rights reserved.
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POLYMER TESTING
ISSN: 0142-9418
Year: 2016
Volume: 55
Page: 318-327
2 . 4 6 4
JCR@2016
5 . 0 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:324
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 13
SCOPUS Cited Count: 12
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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