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author:

Wu, Xiaomin (Wu, Xiaomin.) [1] | Lan, Shuqiong (Lan, Shuqiong.) [2] | Zhang, Guocheng (Zhang, Guocheng.) [3] | Chen, Qizhen (Chen, Qizhen.) [4] | Chen, Huipeng (Chen, Huipeng.) [5] (Scholars:陈惠鹏) | Guo, Tailiang (Guo, Tailiang.) [6] (Scholars:郭太良)

Indexed by:

EI Scopus SCIE

Abstract:

Here, conjugated polymer is added as third component to tune the solution viscosity, morphology, and function of small molecule (SM) based bulk-hetero-junction (BHJ) solar cells, which are fabricated using blade coating. Novel information about the effect of blade coating speed on the nanoscale morphology and function of ternary blend solar cells is provided. The crystal sizes increase with an increase of coating speed for both binary and ternary blends, while the addition of the third component tends to favor smaller SM crystal grains and improves the connectivity of SM crystals. Small angle neutron scattering experiments provide the first clear experimental evidence that the addition of the third component would significantly impact the fullerene phase separation, which is crucial for bimolecular recombination and charge transport. It shows that for both binary and ternary blends, the concentration and sizes of [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) aggregates increase with an increase of coating speed, while addition of third component does not affect the volume fraction of PCBM aggregates but impacts the size of PCBM aggregates. It is demonstrated that the judicious selection of blade coating speed and addition of conjugated polymer optimize the morphology of SM-BHJ, providing guidelines for high performance SM-BHJs from roll-to-roll production.

Keyword:

blade coatings fullerene phase separation neutron scattering organic photovoltaics ternary blend solar cells

Community:

  • [ 1 ] [Wu, Xiaomin]Fuzhou Univ, Natl & Local United Engn Lab Flat Panel Display T, Inst Optoelect Display, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Lan, Shuqiong]Fuzhou Univ, Natl & Local United Engn Lab Flat Panel Display T, Inst Optoelect Display, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Zhang, Guocheng]Fuzhou Univ, Natl & Local United Engn Lab Flat Panel Display T, Inst Optoelect Display, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Chen, Qizhen]Fuzhou Univ, Natl & Local United Engn Lab Flat Panel Display T, Inst Optoelect Display, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Chen, Huipeng]Fuzhou Univ, Natl & Local United Engn Lab Flat Panel Display T, Inst Optoelect Display, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Guo, Tailiang]Fuzhou Univ, Natl & Local United Engn Lab Flat Panel Display T, Inst Optoelect Display, Fuzhou 350002, Fujian, Peoples R China
  • [ 7 ] [Zhang, Guocheng]Fujian Univ Technol, Coll Informat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China

Reprint 's Address:

  • 陈惠鹏

    [Chen, Huipeng]Fuzhou Univ, Natl & Local United Engn Lab Flat Panel Display T, Inst Optoelect Display, Fuzhou 350002, Fujian, Peoples R China

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Source :

ADVANCED FUNCTIONAL MATERIALS

ISSN: 1616-301X

Year: 2017

Issue: 40

Volume: 27

1 3 . 3 2 5

JCR@2017

1 8 . 5 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:306

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 33

SCOPUS Cited Count: 31

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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