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Abstract:
Electrochemiluminescence (ECL) emission of gold nanoparticles (Au NPs) loaded graphitic carbon nitride nanosheets (Au-CNN nanohybrids) can be modulated by the Au content. On the basis, a signal-on ECL sensor for detecting cyanide, a widespread toxic chemical, has been developed in this work. The sensor utilizes cyanide-mediated etching of Au NPs to recover the ECL emission of Au-CNN nanohybrids initially inhibited by Fo rster resonance energy transfer (FRET) from CNNs to Au NPs. The ECL sensor has a sensitive response to cyanide in the range of 50 nM to 1mM with a detection limit of 50 nM, and shows high specificity due to the high affinity of Au-cyanide complex. The proposed FRET modulated ECL sensor may prove valuable in future environmental monitoring. (c) 2017 Elsevier Ltd. All rights reserved.
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ELECTROCHIMICA ACTA
ISSN: 0013-4686
Year: 2018
Volume: 261
Page: 29-34
5 . 3 8 3
JCR@2018
5 . 5 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:209
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 19
SCOPUS Cited Count: 21
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 0
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