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author:

Feng, Yingying (Feng, Yingying.) [1] | Shi, Lei (Shi, Lei.) [2] | Wu, Haishan (Wu, Haishan.) [3] | Chen, Lichan (Chen, Lichan.) [4] | Chi, Yuwu (Chi, Yuwu.) [5] (Scholars:池毓务)

Indexed by:

EI Scopus SCIE

Abstract:

Electrochemiluminescence (ECL) emission of gold nanoparticles (Au NPs) loaded graphitic carbon nitride nanosheets (Au-CNN nanohybrids) can be modulated by the Au content. On the basis, a signal-on ECL sensor for detecting cyanide, a widespread toxic chemical, has been developed in this work. The sensor utilizes cyanide-mediated etching of Au NPs to recover the ECL emission of Au-CNN nanohybrids initially inhibited by Fo rster resonance energy transfer (FRET) from CNNs to Au NPs. The ECL sensor has a sensitive response to cyanide in the range of 50 nM to 1mM with a detection limit of 50 nM, and shows high specificity due to the high affinity of Au-cyanide complex. The proposed FRET modulated ECL sensor may prove valuable in future environmental monitoring. (c) 2017 Elsevier Ltd. All rights reserved.

Keyword:

Cyanide Electrochemiluminescent sensor Forster resonance energy transfer Graphitic carbon nitride nanosheets

Community:

  • [ 1 ] [Feng, Yingying]Fuzhou Univ, Coll Chem, Key Lab Analyt Sci Food Safety & Biol, Minist Educ,Fujian Prov Key Lab Anal & Detect Foo, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Shi, Lei]Fuzhou Univ, Coll Chem, Key Lab Analyt Sci Food Safety & Biol, Minist Educ,Fujian Prov Key Lab Anal & Detect Foo, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Wu, Haishan]Fuzhou Univ, Coll Chem, Key Lab Analyt Sci Food Safety & Biol, Minist Educ,Fujian Prov Key Lab Anal & Detect Foo, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [Chi, Yuwu]Fuzhou Univ, Coll Chem, Key Lab Analyt Sci Food Safety & Biol, Minist Educ,Fujian Prov Key Lab Anal & Detect Foo, Fuzhou 350108, Fujian, Peoples R China
  • [ 5 ] [Chen, Lichan]Huaqiao Univ, Coll Chem Engn, Xiamen 361021, Peoples R China
  • [ 6 ] [Feng, Yingying]Coll Chem Engn, Fuzhou 350108, Fujian, Peoples R China

Reprint 's Address:

  • 池毓务

    [Chi, Yuwu]Fuzhou Univ, Coll Chem, Key Lab Analyt Sci Food Safety & Biol, Minist Educ,Fujian Prov Key Lab Anal & Detect Foo, Fuzhou 350108, Fujian, Peoples R China;;[Chen, Lichan]Huaqiao Univ, Coll Chem Engn, Xiamen 361021, Peoples R China

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Source :

ELECTROCHIMICA ACTA

ISSN: 0013-4686

Year: 2018

Volume: 261

Page: 29-34

5 . 3 8 3

JCR@2018

5 . 5 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:209

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 19

SCOPUS Cited Count: 21

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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