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author:

Feng, Yingying (Feng, Yingying.) [1] | Shi, Lei (Shi, Lei.) [2] | Wu, Haishan (Wu, Haishan.) [3] | Chen, Lichan (Chen, Lichan.) [4] | Chi, Yuwu (Chi, Yuwu.) [5]

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EI

Abstract:

Electrochemiluminescence (ECL) emission of gold nanoparticles (Au NPs) loaded graphitic carbon nitride nanosheets (Au-CNN nanohybrids) can be modulated by the Au content. On the basis, a signal-on ECL sensor for detecting cyanide, a widespread toxic chemical, has been developed in this work. The sensor utilizes cyanide-mediated etching of Au NPs to recover the ECL emission of Au-CNN nanohybrids initially inhibited by Frster resonance energy transfer (FRET) from CNNs to Au NPs. The ECL sensor has a sensitive response to cyanide in the range of 50 nM to 1 mM with a detection limit of 50 nM, and shows high specificity due to the high affinity of Au-cyanide complex. The proposed FRET modulated ECL sensor may prove valuable in future environmental monitoring. © 2017 Elsevier Ltd

Keyword:

Carbon nitride Cyanides Energy transfer Etching Forster resonance energy transfer Gold compounds Gold nanoparticles Nanosheets Nanostructured materials Nitrides

Community:

  • [ 1 ] [Feng, Yingying]Key Laboratory for Analytical Science of Food Safety and Biology, Ministry of Education, Fujian Provincial Key Laboratory of Analysis and Detection for Food Safety, College of Chemistry, Fuzhou University, Fuzhou; Fujian; 350108, China
  • [ 2 ] [Feng, Yingying]College of Chemical Engineering, Fuzhou; Fujian; 350108, China
  • [ 3 ] [Shi, Lei]Key Laboratory for Analytical Science of Food Safety and Biology, Ministry of Education, Fujian Provincial Key Laboratory of Analysis and Detection for Food Safety, College of Chemistry, Fuzhou University, Fuzhou; Fujian; 350108, China
  • [ 4 ] [Wu, Haishan]Key Laboratory for Analytical Science of Food Safety and Biology, Ministry of Education, Fujian Provincial Key Laboratory of Analysis and Detection for Food Safety, College of Chemistry, Fuzhou University, Fuzhou; Fujian; 350108, China
  • [ 5 ] [Chen, Lichan]College of Chemical Engineering, Huaqiao University, Xiamen; 361021, China
  • [ 6 ] [Chi, Yuwu]Key Laboratory for Analytical Science of Food Safety and Biology, Ministry of Education, Fujian Provincial Key Laboratory of Analysis and Detection for Food Safety, College of Chemistry, Fuzhou University, Fuzhou; Fujian; 350108, China

Reprint 's Address:

  • [chi, yuwu]key laboratory for analytical science of food safety and biology, ministry of education, fujian provincial key laboratory of analysis and detection for food safety, college of chemistry, fuzhou university, fuzhou; fujian; 350108, china

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Source :

Electrochimica Acta

ISSN: 0013-4686

Year: 2018

Volume: 261

Page: 29-34

5 . 3 8 3

JCR@2018

5 . 5 0 0

JCR@2023

ESI HC Threshold:209

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 21

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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