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author:

Feng, Y. (Feng, Y..) [1] | Shi, L. (Shi, L..) [2] | Wu, H. (Wu, H..) [3] | Chen, L. (Chen, L..) [4] | Chi, Y. (Chi, Y..) [5]

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Scopus

Abstract:

Electrochemiluminescence (ECL) emission of gold nanoparticles (Au NPs) loaded graphitic carbon nitride nanosheets (Au-CNN nanohybrids) can be modulated by the Au content. On the basis, a signal-on ECL sensor for detecting cyanide, a widespread toxic chemical, has been developed in this work. The sensor utilizes cyanide-mediated etching of Au NPs to recover the ECL emission of Au-CNN nanohybrids initially inhibited by Fӧrster resonance energy transfer (FRET) from CNNs to Au NPs. The ECL sensor has a sensitive response to cyanide in the range of 50 nM to 1 mM with a detection limit of 50 nM, and shows high specificity due to the high affinity of Au-cyanide complex. The proposed FRET modulated ECL sensor may prove valuable in future environmental monitoring. © 2017 Elsevier Ltd

Keyword:

Cyanide; Electrochemiluminescent sensor; Fӧrster resonance energy transfer; Graphitic carbon nitride nanosheets

Community:

  • [ 1 ] [Feng, Y.]Key Laboratory for Analytical Science of Food Safety and Biology, Ministry of Education, Fujian Provincial Key Laboratory of Analysis and Detection for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
  • [ 2 ] [Feng, Y.]College of Chemical Engineering, Fuzhou, Fujian 350108, China
  • [ 3 ] [Shi, L.]Key Laboratory for Analytical Science of Food Safety and Biology, Ministry of Education, Fujian Provincial Key Laboratory of Analysis and Detection for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
  • [ 4 ] [Wu, H.]Key Laboratory for Analytical Science of Food Safety and Biology, Ministry of Education, Fujian Provincial Key Laboratory of Analysis and Detection for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
  • [ 5 ] [Chen, L.]College of Chemical Engineering, Huaqiao University, Xiamen, 361021, China
  • [ 6 ] [Chi, Y.]Key Laboratory for Analytical Science of Food Safety and Biology, Ministry of Education, Fujian Provincial Key Laboratory of Analysis and Detection for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China

Reprint 's Address:

  • [Chi, Y.]Key Laboratory for Analytical Science of Food Safety and Biology, Ministry of Education, Fujian Provincial Key Laboratory of Analysis and Detection for Food Safety, College of Chemistry, Fuzhou UniversityChina

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Source :

Electrochimica Acta

ISSN: 0013-4686

Year: 2018

Volume: 261

Page: 29-34

5 . 3 8 3

JCR@2018

5 . 5 0 0

JCR@2023

ESI HC Threshold:209

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 21

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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