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author:

Wen, Zhaojun (Wen, Zhaojun.) [1] | Duan, Xinping (Duan, Xinping.) [2] | Hu, Menglin (Hu, Menglin.) [3] | Cao, Yanning (Cao, Yanning.) [4] (Scholars:曹彦宁) | Ye, Linmin (Ye, Linmin.) [5] | Jiang, Lilong (Jiang, Lilong.) [6] (Scholars:江莉龙) | Yuan, Youzhu (Yuan, Youzhu.) [7]

Indexed by:

EI Scopus SCIE CSCD

Abstract:

In this study, the effects of copper (Cu) additive on the catalytic performance of Ag/SBA-15 in complete soot combustion were investigated. The soot combustion performance of bimetallic Ag-Cu/SBA-15 catalysts was higher than that of monometallic Ag and Cu catalysts. The optimum catalytic performance was acquired with the 5Ag(1)-Cu-0.1/SBA-15 catalyst, on which the soot combustion starts at T-ig = 225 degrees C with a T-50 = 285 degrees C. The temperature for 50% of soot combustion was lower than that of conventional Ag-based catalysts to more than 50 degrees C (Aneggi et al., 2009). Physicochemical characterizations of the catalysts indicated that addition of Cu into Ag could form smaller bimetallic Ag-Cu nanolloy particles, downsizing the mean particle size from 3.7 nm in monometallic catalyst to 2.6 nm in bimetallic Ag-Cu catalyst. Further experiments revealed that Ag and Cu species elicited synergistic effects, subsequently increasing the content of surface active oxygenspecies. As a result, the structure modifications of Ag by the addition of Cu strongly intensified the catalytic performance. (C) 2017 The Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V.

Keyword:

Bimetallic catalyst Copper Nanoalloy Silver Soot combustion Thermal stability

Community:

  • [ 1 ] [Wen, Zhaojun]Xiamen Univ, Coll Chem & Chem Engn, Natl Engn Lab Green Chem Prod Alcohols Ethers Est, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
  • [ 2 ] [Duan, Xinping]Xiamen Univ, Coll Chem & Chem Engn, Natl Engn Lab Green Chem Prod Alcohols Ethers Est, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
  • [ 3 ] [Hu, Menglin]Xiamen Univ, Coll Chem & Chem Engn, Natl Engn Lab Green Chem Prod Alcohols Ethers Est, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
  • [ 4 ] [Ye, Linmin]Xiamen Univ, Coll Chem & Chem Engn, Natl Engn Lab Green Chem Prod Alcohols Ethers Est, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
  • [ 5 ] [Yuan, Youzhu]Xiamen Univ, Coll Chem & Chem Engn, Natl Engn Lab Green Chem Prod Alcohols Ethers Est, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
  • [ 6 ] [Cao, Yanning]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China
  • [ 7 ] [Jiang, Lilong]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address:

  • 江莉龙

    [Yuan, Youzhu]Xiamen Univ, Coll Chem & Chem Engn, Natl Engn Lab Green Chem Prod Alcohols Ethers Est, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China;;[Jiang, Lilong]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China

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Source :

JOURNAL OF ENVIRONMENTAL SCIENCES

ISSN: 1001-0742

CN: 11-2629/X

Year: 2018

Volume: 64

Page: 122-129

3 . 5 5 6

JCR@2018

5 . 9 0 0

JCR@2023

ESI Discipline: ENVIRONMENT/ECOLOGY;

ESI HC Threshold:222

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 12

SCOPUS Cited Count: 14

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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