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In this study, the effects of copper (Cu) additive on the catalytic performance of Ag/SBA-15 in complete soot combustion were investigated. The soot combustion performance of bimetallic Ag-Cu/SBA-15 catalysts was higher than that of monometallic Ag and Cu catalysts. The optimum catalytic performance was acquired with the 5Ag(1)-Cu-0.1/SBA-15 catalyst, on which the soot combustion starts at T-ig = 225 degrees C with a T-50 = 285 degrees C. The temperature for 50% of soot combustion was lower than that of conventional Ag-based catalysts to more than 50 degrees C (Aneggi et al., 2009). Physicochemical characterizations of the catalysts indicated that addition of Cu into Ag could form smaller bimetallic Ag-Cu nanolloy particles, downsizing the mean particle size from 3.7 nm in monometallic catalyst to 2.6 nm in bimetallic Ag-Cu catalyst. Further experiments revealed that Ag and Cu species elicited synergistic effects, subsequently increasing the content of surface active oxygenspecies. As a result, the structure modifications of Ag by the addition of Cu strongly intensified the catalytic performance. (C) 2017 The Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V.
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JOURNAL OF ENVIRONMENTAL SCIENCES
ISSN: 1001-0742
CN: 11-2629/X
Year: 2018
Volume: 64
Page: 122-129
3 . 5 5 6
JCR@2018
5 . 9 0 0
JCR@2023
ESI Discipline: ENVIRONMENT/ECOLOGY;
ESI HC Threshold:222
JCR Journal Grade:2
CAS Journal Grade:3
Cited Count:
WoS CC Cited Count: 12
SCOPUS Cited Count: 14
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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