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author:

Wen, Zhaojun (Wen, Zhaojun.) [1] | Duan, Xinping (Duan, Xinping.) [2] | Hu, Menglin (Hu, Menglin.) [3] | Cao, Yanning (Cao, Yanning.) [4] | Ye, Linmin (Ye, Linmin.) [5] | Jiang, Lilong (Jiang, Lilong.) [6] | Yuan, Youzhu (Yuan, Youzhu.) [7]

Indexed by:

EI CSCD

Abstract:

In this study, the effects of copper (Cu) additive on the catalytic performance of Ag/SBA-15 in complete soot combustion were investigated. The soot combustion performance of bimetallic Ag–Cu/SBA-15 catalysts was higher than that of monometallic Ag and Cu catalysts. The optimum catalytic performance was acquired with the 5Ag1-Cu0.1/SBA-15 catalyst, on which the soot combustion starts at Tig = 225°C with a T50 = 285°C. The temperature for 50% of soot combustion was lower than that of conventional Ag-based catalysts to more than 50°C (Aneggi et al., 2009). Physicochemical characterizations of the catalysts indicated that addition of Cu into Ag could form smaller bimetallic Ag–Cu nanolloy particles, downsizing the mean particle size from 3.7 nm in monometallic catalyst to 2.6 nm in bimetallic Ag–Cu catalyst. Further experiments revealed that Ag and Cu species elicited synergistic effects, subsequently increasing the content of surface active oxygen species. As a result, the structure modifications of Ag by the addition of Cu strongly intensified the catalytic performance. © 2017

Keyword:

Catalysts Combustion Copper Dust Ionization of gases Particle size Silver Soot Temperature Thermodynamic stability

Community:

  • [ 1 ] [Wen, Zhaojun]State Key Laboratory of Physical Chemistry of Solid Surfaces, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen; 361005, China
  • [ 2 ] [Duan, Xinping]State Key Laboratory of Physical Chemistry of Solid Surfaces, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen; 361005, China
  • [ 3 ] [Hu, Menglin]State Key Laboratory of Physical Chemistry of Solid Surfaces, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen; 361005, China
  • [ 4 ] [Cao, Yanning]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou; 350002, China
  • [ 5 ] [Ye, Linmin]State Key Laboratory of Physical Chemistry of Solid Surfaces, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen; 361005, China
  • [ 6 ] [Jiang, Lilong]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou; 350002, China
  • [ 7 ] [Yuan, Youzhu]State Key Laboratory of Physical Chemistry of Solid Surfaces, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen; 361005, China

Reprint 's Address:

  • [jiang, lilong]national engineering research center of chemical fertilizer catalyst, fuzhou university, fuzhou; 350002, china

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Source :

Journal of Environmental Sciences (China)

ISSN: 1001-0742

Year: 2018

Volume: 64

Page: 122-129

3 . 5 5 6

JCR@2018

5 . 9 0 0

JCR@2023

ESI HC Threshold:222

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 14

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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