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[期刊论文]

Improving device performance of n-type organic field-effect transistors via doping with a p-type organic semiconductor

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author:

Lan, Shuqiong (Lan, Shuqiong.) [1] | Yan, Yujie (Yan, Yujie.) [2] | Yang, Huihuang (Yang, Huihuang.) [3] | Unfold

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Abstract:

Low-power complementary organic circuits need to combine p-channel organic field-effect transistors (OFETs) and n-channel OFETs, which are based on p-type and n-type organic semiconductors, respectively. Unfortunately, the performance of n-type organic semiconductors still lags behind that of p-type organic semiconductors. In this work, the performance of solution-processed n-type OFETs was improved via a facile effective route, by blending a p-type organic semiconductor into the n-type polymer semiconductor. The effect of the p-type organic semiconductor additive on the morphology and charge transport was systematically investigated. It showed that the mobility, on/off ratio and stability of the n-type OFETs were significantly improved with incorporation of the p-type semiconductor. The p-type organic semiconductor functioned as a trap center for minority holes and decreased the trap density of the dielectric surface, resulting in an enhancement of the OFET performance. Moreover, blending with an appropriate amount of p-type organic semiconductor also benefited to reset polymer semiconductors stacking order into the direction that promoted charge transport. However, excess p-type semiconductor addition deteriorated the n-channel characteristics due to the formation of a percolation network, providing a pathway for hole transport. To the best of our knowledge, this is the first report about improving the performance of n-type polymer transistors by simply blending with a p-type organic semiconductor.

Community:

  • [ 1 ] [Lan, Shuqiong]Fuzhou Univ, Inst Optoelect Display, Natl & Local United Engn Lab Flat Panel Display T, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Yan, Yujie]Fuzhou Univ, Inst Optoelect Display, Natl & Local United Engn Lab Flat Panel Display T, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Yang, Huihuang]Fuzhou Univ, Inst Optoelect Display, Natl & Local United Engn Lab Flat Panel Display T, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Zhang, Guocheng]Fuzhou Univ, Inst Optoelect Display, Natl & Local United Engn Lab Flat Panel Display T, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Ye, Yun]Fuzhou Univ, Inst Optoelect Display, Natl & Local United Engn Lab Flat Panel Display T, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Li, Fushan]Fuzhou Univ, Inst Optoelect Display, Natl & Local United Engn Lab Flat Panel Display T, Fuzhou 350002, Fujian, Peoples R China
  • [ 7 ] [Chen, Huipeng]Fuzhou Univ, Inst Optoelect Display, Natl & Local United Engn Lab Flat Panel Display T, Fuzhou 350002, Fujian, Peoples R China
  • [ 8 ] [Guo, Tailiang]Fuzhou Univ, Inst Optoelect Display, Natl & Local United Engn Lab Flat Panel Display T, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address:

  • 陈惠鹏

    [Chen, Huipeng]Fuzhou Univ, Inst Optoelect Display, Natl & Local United Engn Lab Flat Panel Display T, Fuzhou 350002, Fujian, Peoples R China

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Source :

JOURNAL OF MATERIALS CHEMISTRY C

ISSN: 2050-7526

Year: 2019

Issue: 15

Volume: 7

Page: 4543-4550

7 . 0 5 9

JCR@2019

5 . 7 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:236

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 42

SCOPUS Cited Count: 45

30 Days PV: 1

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