Cu-Catalyzed Denitrogenative Transannulation of 3-Aminoindazoles To Assemble 1-Aminoisoquinolines and 3-Aminobenzothiophenes - Details

author：

Zhou, Yao (Zhou, Yao.) ^[1] | Wang, Ya (Wang, Ya.) ^[2] | Lou, Yixian (Lou, Yixian.) ^[3] | Song, Qiuling (Song, Qiuling.) ^[4] (Scholars：宋秋玲)

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Abstract：

We　disclose　a　novel　Cu-catalyzed　denitrogenative　transannulation　of　3-aminoindazoles　to　afford　diverse　functionalized　3-aminobenzothiophenes　and　1-aminoisoquinolines,　in　which　denitrogenative　transannulation　of　3-aminoindazoles　is　reported　for　the　first　time.　This　transformation　proceeds　via　an　＂extrude-and-sew＂　strategy　with　an　unprecedented　radical　reactivity　of　3-aminoindazoles.

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[ 1 ] [Zhou, Yao]Huaqiao Univ, Coll Mat Sci & Engn, Inst Next Generat Matter Transformat, 668 Jimei Blvd, Xiamen 361021, Fujian, Peoples R China
[ 2 ] [Wang, Ya]Huaqiao Univ, Coll Mat Sci & Engn, Inst Next Generat Matter Transformat, 668 Jimei Blvd, Xiamen 361021, Fujian, Peoples R China
[ 3 ] [Song, Qiuling]Huaqiao Univ, Coll Mat Sci & Engn, Inst Next Generat Matter Transformat, 668 Jimei Blvd, Xiamen 361021, Fujian, Peoples R China
[ 4 ] [Lou, Yixian]Zhejiang Univ Technol, Collaborat Innovat Ctr Yangtze River Delta Reg Gr, Hangzhou 310000, Zhejiang, Peoples R China
[ 5 ] [Song, Qiuling]Zhejiang Univ Technol, Collaborat Innovat Ctr Yangtze River Delta Reg Gr, Hangzhou 310000, Zhejiang, Peoples R China
[ 6 ] [Song, Qiuling]Fuzhou Univ, Fujian Univ, Key Lab Mol Synth & Funct Discovery, Coll Chem, Fuzhou 350108, Fujian, Peoples R China

Reprint 's Address：

宋秋玲
[Song, Qiuling]Huaqiao Univ, Coll Mat Sci & Engn, Inst Next Generat Matter Transformat, 668 Jimei Blvd, Xiamen 361021, Fujian, Peoples R China;;[Song, Qiuling]Zhejiang Univ Technol, Collaborat Innovat Ctr Yangtze River Delta Reg Gr, Hangzhou 310000, Zhejiang, Peoples R China;;[Song, Qiuling]Fuzhou Univ, Fujian Univ, Key Lab Mol Synth & Funct Discovery, Coll Chem, Fuzhou 350108, Fujian, Peoples R China

Email：

qsong@hqu.edu.cn

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Version：

Cu-Catalyzed Denitrogenative Transannulation of 3-Aminoindazoles to Assemble 1-Aminoisoquinolines and 3-Aminobenzothiophenes
2019，Organic Letters

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ORGANIC LETTERS

ISSN： 1523-7060

Year： 2019

Issue： 22

Volume： 21

Page： 8869-8873

6 . 0 9 1

JCR@2019

4 . 9 0 0

JCR@2023

ESI Discipline： CHEMISTRY;

ESI HC Threshold：184

JCR Journal Grade：1

CAS Journal Grade：1

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ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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