Cu-Catalyzed Denitrogenative Transannulation of 3-Aminoindazoles to Assemble 1-Aminoisoquinolines and 3-Aminobenzothiophenes - Details

author：

Zhou, Y. (Zhou, Y..) ^[1] | Wang, Y. (Wang, Y..) ^[2] | Lou, Y. (Lou, Y..) ^[3] | Song, Q. (Song, Q..) ^[4]

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Abstract：

We　disclose　a　novel　Cu-catalyzed　denitrogenative　transannulation　of　3-aminoindazoles　to　afford　diverse　functionalized　3-aminobenzothiophenes　and　1-aminoisoquinolines,　in　which　denitrogenative　transannulation　of　3-aminoindazoles　is　reported　for　the　first　time.　This　transformation　proceeds　via　an　＂extrude-and-sew＂　strategy　with　an　unprecedented　radical　reactivity　of　3-aminoindazoles.　©　2019　American　Chemical　Society.

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[ 1 ] [Zhou, Y.]Institute of Next Generation Matter Transformation, College of Materials Science and Engineering, Huaqiao University, 668 Jimei Boulevard, Xiamen, Fujian, 361021, China
[ 2 ] [Wang, Y.]Institute of Next Generation Matter Transformation, College of Materials Science and Engineering, Huaqiao University, 668 Jimei Boulevard, Xiamen, Fujian, 361021, China
[ 3 ] [Lou, Y.]Collaborative Innovation Center of Yangtze River Delta Region Green Pharmaceuticals, Zhejiang University of Technology, Hangzhou, Zhejiang, 310000, China
[ 4 ] [Song, Q.]Institute of Next Generation Matter Transformation, College of Materials Science and Engineering, Huaqiao University, 668 Jimei Boulevard, Xiamen, Fujian, 361021, China
[ 5 ] [Song, Q.]Collaborative Innovation Center of Yangtze River Delta Region Green Pharmaceuticals, Zhejiang University of Technology, Hangzhou, Zhejiang, 310000, China
[ 6 ] [Song, Q.]Fujian University, Key Laboratory of Molecule Synthesis and Function Discovery, College of Chemistry, Fuzhou University, Fuzhou, Fujian, 350108, China

Reprint 's Address：

[Song, Q.]Institute of Next Generation Matter Transformation, College of Materials Science and Engineering, Huaqiao University, 668 Jimei Boulevard, China

Email：

qsong@hqu.edu.cn

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Source ：

Organic Letters

ISSN： 1523-7060

Year： 2019

Issue： 22

Volume： 21

Page： 8869-8873

6 . 0 9 1

JCR@2019

4 . 9 0 0

JCR@2023

ESI HC Threshold：184

JCR Journal Grade：1

CAS Journal Grade：1

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ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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