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author:

Yang, Weiqiang (Yang, Weiqiang.) [1] | Zhang, Guiyun (Zhang, Guiyun.) [2] | Ni, Jiancong (Ni, Jiancong.) [3] | Lin, Zhenyu (Lin, Zhenyu.) [4] (Scholars:林振宇)

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Scopus SCIE

Abstract:

Fluorescent nanoparticles were prepared by encapsulating carbon dots (CDs) within silica spheres and then modifying these spheres with amino groups (CD@SiO2-NH2). On the basis of the silver mirror reaction, Ag+ assembled on the surface of CD@SiO2-NH2 is reduced to silver nanoparticles (AgNPs) by formaldehyde. The in-situ grown AgNPs cause a visually distinguishable fluorescence enhancement. This metal-enhanced effect was investigated by transmission electron microscopy and spectroscopic characterization, and the relevant conditions were optimized. CD@SiO2-NH2-Ag+ fluorescent probes were loaded onto nano-sponge pieces for the analysis of formaldehyde gas. The blue fluorescence emission (peaking at 466 nm) in response to formaldehyde is greatly enhanced (up to 5.2 times) over other species. There is a linear relationship between the fluorescence enhancement and formaldehyde gas concentration in the range of 10 ppb to 1 ppm, and the detection limit is 3 ppb. The fluorimetric assay needs 30 min for the reaction, and the fluorescent nano-sponge pieces are disposable.

Keyword:

Environmental pollutants Fluorescent nanoparticles Gas determination Metal-enhanced fluorescence Nano-sponge Silica spheres Silver mirror reaction Visual detection

Community:

  • [ 1 ] [Yang, Weiqiang]Minnan Normal Univ, Coll Chem & Environm, Fujian Prov Key Lab Modern Analyt Sci & Separat T, Fujian Prov Key Lab Pollut Monitoring & Control, Zhangzhou 363000, Peoples R China
  • [ 2 ] [Ni, Jiancong]Minnan Normal Univ, Coll Chem & Environm, Fujian Prov Key Lab Modern Analyt Sci & Separat T, Fujian Prov Key Lab Pollut Monitoring & Control, Zhangzhou 363000, Peoples R China
  • [ 3 ] [Yang, Weiqiang]Fuzhou Univ, Coll Chem, MOE,Key Lab Analyt Sci Food Safety & Biol, Fujian Prov Key Lab Anal & Detect Technol Food Sa, Fuzhou 350116, Peoples R China
  • [ 4 ] [Lin, Zhenyu]Fuzhou Univ, Coll Chem, MOE,Key Lab Analyt Sci Food Safety & Biol, Fujian Prov Key Lab Anal & Detect Technol Food Sa, Fuzhou 350116, Peoples R China
  • [ 5 ] [Zhang, Guiyun]Zhangzhou Inst Technol, Fujian Prov Collaborat Innovat Inst Food Ind Tech, Zhangzhou 363000, Peoples R China

Reprint 's Address:

  • 林振宇

    [Ni, Jiancong]Minnan Normal Univ, Coll Chem & Environm, Fujian Prov Key Lab Modern Analyt Sci & Separat T, Fujian Prov Key Lab Pollut Monitoring & Control, Zhangzhou 363000, Peoples R China;;[Lin, Zhenyu]Fuzhou Univ, Coll Chem, MOE,Key Lab Analyt Sci Food Safety & Biol, Fujian Prov Key Lab Anal & Detect Technol Food Sa, Fuzhou 350116, Peoples R China

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Source :

MICROCHIMICA ACTA

ISSN: 0026-3672

Year: 2020

Issue: 2

Volume: 187

5 . 8 3 3

JCR@2020

5 . 4 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:160

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 18

SCOPUS Cited Count: 19

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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