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Ferro/piezoelectric transparent materials with both excellent piezoelectricity and transparency are of great interest for irreplaceable applications in numerous fields such as photoacoustic imaging and transparent robots. Nevertheless, developing a lead-free ferroelectric ceramic that meets both distinct transparency and high piezoelectricity has always been challenging. Herein, the simple single Sm3+ doped KNN ferroelectric ceramics (xSm) are designed to improve transparency and achieve reasonable piezoelectricity. The results indicate that although the donor doping effect of Sm3+ significantly improves the transparency by mainly causing grain refinement and densification improvement, it also enhances the relaxor behavior of KNN ceramics and weakens the piezoelectricity. Despite this, with proper Sm doping, reasonable piezoelectricity can still be achieved in the xSm transparent ceramics without causing a significant decrease in Curie temperature. Ultimately, excellent comprehensive performance was achieved in the 1.0 Sm ceramic (T~65% at 900 nm, TC~395 °C, d33~65 pC/N), competitively in the KNN-based transparent ceramics. In force sensitivity testing, the 1.0 Sm ceramic also exhibits prominent force response electrical output characteristics, which is expected to be applied in smart windows that require real-time pressure detection. This work furnishes a methodology for the fabrication of KNN-based transparent piezoceramics, while contemporaneously recommending innovative perspectives for broadening their range of applications. © The Author(s) 2025.
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Microstructures
ISSN: 2770-2995
Year: 2025
Issue: 3
Volume: 5
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ESI Highly Cited Papers on the List: 0 Unfold All
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