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author:

Han, Longfei (Han, Longfei.) [1] | Zhang, Mengdan (Zhang, Mengdan.) [2] | Cao, Yukun (Cao, Yukun.) [3] | Zhang, Xinru (Zhang, Xinru.) [4] | Liao, Can (Liao, Can.) [5] | Cheng, Liying (Cheng, Liying.) [6] | Gu, Qiang (Gu, Qiang.) [7] | Kan, Yongchun (Kan, Yongchun.) [8] | Zhu, Jixin (Zhu, Jixin.) [9] | Hu, Yuan (Hu, Yuan.) [10]

Indexed by:

Scopus SCIE

Abstract:

Lithium (Li) metal batteries have garnered significant attention due to their high energy density. However, the safety concerns associated with Li-metal batteries need to be addressed for their commercial viability. Most research has focused on the safety of separators and electrolytes, yet little emphasis is placed on the heat safety of lithium metal. In an out-of-control scenario, the combustion of lithium metal can release significantly more heat compared to other components. In this study, a highly safe composite Li metal anode is introduced fabricated by repeatedly rolling copper (Cu) powder and lithium metal. Electrochemical tests show that the Cu/Li anode can withstand up to 200 cycles, far surpassing the 50-cycle lifespan of conventional Li metal anodes. Safety test results indicate that the Li/Cu composite anode possesses self-extinguishing properties, significantly mitigating the safety risks associated with lithium metal batteries. Thermal runaway tests on the 1.0 Ah pouch cell demonstrate that the Li/Cu composite anode exhibits excellent safety characteristics, effectively inhibiting thermal runaway phenomena. The proposed straightforward, and high-safety Li/Cu composite anode can enhance the safety profile of lithium metal batteries and provide crucial technical support for their industrial application.

Keyword:

fire-safety lithium anode lithium metal batteries thermal runaway

Community:

  • [ 1 ] [Han, Longfei]Univ Sci & Technol China, State Key Lab Fire Sci, Hefei 230026, Anhui, Peoples R China
  • [ 2 ] [Cao, Yukun]Univ Sci & Technol China, State Key Lab Fire Sci, Hefei 230026, Anhui, Peoples R China
  • [ 3 ] [Zhang, Xinru]Univ Sci & Technol China, State Key Lab Fire Sci, Hefei 230026, Anhui, Peoples R China
  • [ 4 ] [Cheng, Liying]Univ Sci & Technol China, State Key Lab Fire Sci, Hefei 230026, Anhui, Peoples R China
  • [ 5 ] [Gu, Qiang]Univ Sci & Technol China, State Key Lab Fire Sci, Hefei 230026, Anhui, Peoples R China
  • [ 6 ] [Kan, Yongchun]Univ Sci & Technol China, State Key Lab Fire Sci, Hefei 230026, Anhui, Peoples R China
  • [ 7 ] [Zhu, Jixin]Univ Sci & Technol China, State Key Lab Fire Sci, Hefei 230026, Anhui, Peoples R China
  • [ 8 ] [Hu, Yuan]Univ Sci & Technol China, State Key Lab Fire Sci, Hefei 230026, Anhui, Peoples R China
  • [ 9 ] [Han, Longfei]Shandong Univ Sci & Technol, State Key Lab Min Disaster Prevent & Control, Cofounded Shandong Prov, Qingdao 266590, Shandong, Peoples R China
  • [ 10 ] [Zhang, Mengdan]Shandong Univ Sci & Technol, State Key Lab Min Disaster Prevent & Control, Cofounded Shandong Prov, Qingdao 266590, Shandong, Peoples R China
  • [ 11 ] [Han, Longfei]Shandong Univ Sci & Technol Qingdao, Minist Sci & Technol, Qingdao 266590, Shandong, Peoples R China
  • [ 12 ] [Zhang, Mengdan]Shandong Univ Sci & Technol Qingdao, Minist Sci & Technol, Qingdao 266590, Shandong, Peoples R China
  • [ 13 ] [Han, Longfei]Shandong Univ Sci & Technol, Coll Safety & Environm Engn, Qingdao 266590, Shandong, Peoples R China
  • [ 14 ] [Zhang, Mengdan]Shandong Univ Sci & Technol, Coll Safety & Environm Engn, Qingdao 266590, Shandong, Peoples R China
  • [ 15 ] [Liao, Can]Fuzhou Univ, Coll Mat Sci & Engn, Fujian Engn Res Ctr, High Energy Batteries & New Energy Equipment & Sys, Fuzhou 350108, Fujian, Peoples R China

Reprint 's Address:

  • [Kan, Yongchun]Univ Sci & Technol China, State Key Lab Fire Sci, Hefei 230026, Anhui, Peoples R China;;[Hu, Yuan]Univ Sci & Technol China, State Key Lab Fire Sci, Hefei 230026, Anhui, Peoples R China

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Source :

ADVANCED FUNCTIONAL MATERIALS

ISSN: 1616-301X

Year: 2025

1 8 . 5 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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