Sodium　ion　hybrid　capacitors　(SIHCs)　are　garnering　substantial　interest　in　the　energy　storage　field　due　to　their　unique　capability　to　integrate　high　energy　density　and　power　density　with　the　economic　advantages　of　abundant　sodium　resources.　However,　the　kinetic　mismatch　between　battery-type　anodes　and　capacitor-type　cathodes　presents　a　significant　obstacle,　severely　limiting　the　performance　potential　of　high-performance　SIHCs.　Herein,　we　report　the　development　of　a　favorable　pseudocapacitive　Na+　storage　nanohybrid,　featuring　VC　nanodots　confined　within　an　N-doped　carbon　nanofiber　network　(VC@N-CNFs),　which　has　been　successfully　applied　to　SIHCs.　The　integration　of　VC　nanodots　with　a　conductive　carbon　fiber　framework　significantly　enhances　electron　transport　and　provides　ample　interface　between　the　electrolyte　and　VC　active　material,　thereby　effectively　improving　the　reaction　kinetics　of　the　anode.　Consequently,　the　VC@N-CNFs　demonstrate　exceptional　sodium　storage　capability,　achieving　a　high　capacity　of　160.2　mA　h　g-1　at　1　A　g-1　after　2000　cycles.　Thanks　to　the　favorable　kinetic　matching　between　the　anode　and　cathode,　the　assembled　SIHCs　exhibit　high　energy　and　power　densities　of　97.8　W　h　kg-1　and　4118.3　W　kg-1,　respectively,　alongside　remarkable　cycling　performance,　retaining　73.5%　of　their　capacity　after　6000　cycles.　©　2025　American　Chemical　Society.