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author:

Li, X.-R. (Li, X.-R..) [1] | Zhang, L. (Zhang, L..) [2] | Lin, Z.-K. (Lin, Z.-K..) [3] | Yang, B.-M. (Yang, B.-M..) [4]

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Abstract:

An efficient and direct approach of dearomatizing nitration of α-substituted β-naphthols with tert-butyl nitrite has been successfully developed under mild conditions. This innovative catalyst-free method enables the synthesis of cyclic ketones featuring an all-substituted carbon center in good yields. The mechanistic studies indicate that the formation of the C─N bond is achieved through radical–radical coupling. © 2025 Wiley-VCH GmbH.

Keyword:

2-naphthol Dearomatization Nitration Radical coupling tert-butyl nitrite

Community:

  • [ 1 ] [Li X.-R.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 2 ] [Li X.-R.]The International Joint Institute of Tianjin University, Fuzhou, Tianjin University, Tianjin, 300072, China
  • [ 3 ] [Zhang L.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 4 ] [Zhang L.]The International Joint Institute of Tianjin University, Fuzhou, Tianjin University, Tianjin, 300072, China
  • [ 5 ] [Lin Z.-K.]The International Joint Institute of Tianjin University, Fuzhou, Tianjin University, Tianjin, 300072, China
  • [ 6 ] [Yang B.-M.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 7 ] [Yang B.-M.]The International Joint Institute of Tianjin University, Fuzhou, Tianjin University, Tianjin, 300072, China
  • [ 8 ] [Yang B.-M.]State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, 730000, China

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Source :

Asian Journal of Organic Chemistry

ISSN: 2193-5815

Year: 2025

Issue: 6

Volume: 14

2 . 8 0 0

JCR@2023

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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