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author:

Wang, Zhenshuai (Wang, Zhenshuai.) [1] | Zhang, Dai (Zhang, Dai.) [2] | Chen, Jianguo (Chen, Jianguo.) [3] | Hong, Ruoyu (Hong, Ruoyu.) [4] | Li, Minglin (Li, Minglin.) [5]

Indexed by:

Scopus SCIE

Abstract:

Rechargeable graphene-based aluminum-ion batteries (AIBs) are recognized as a promising energy storage system. The impact of the macroscopic morphology of graphene electrodes on electrochemical performance, however, has been minimally explored. Reduced graphene oxide (rGO) was synthesized via a modified Hummers method and hydrothermal reduction, utilizing natural flake graphite as the starting material. The traditional electrode preparation process was employed, where the active material, conductive agent, and binder were combined to form a slurry for coating and subsequent drying, resulting in the rGO electrode. Aerogel-shaped rGO (rGOA) and film-shaped rGO (rGOF) electrodes were additionally crafted through freeze-drying and filtration drying techniques. Among the three distinct rGO electrode morphologies tested as cathodes in AIBs, the rGOF electrode demonstrated outstanding electrochemical characteristics, including a high specific capacity of 149.3 mAh/g at 500 mA/g, a substantial rate performance of 55.3 mAh/g at 10,000 mA/g, and an impressive long-term cycling stability of 94.5 mAh/g with a Coulombic efficiency of 95.8 % at 5000 mA/g after 10,000 cycles. These superior properties are attributed to the rGOF's binder-free, densely packed structure. The findings suggest that the rGOF electrode holds significant potential as a cathode material for AIBs, offering advantages in both scalable preparation and superior electrochemical performance.

Keyword:

Aluminum ion batteries Electrochemical performance Electrodes Macroscopic morphology Reduced graphene oxide

Community:

  • [ 1 ] [Wang, Zhenshuai]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Zhang, Dai]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China
  • [ 3 ] [Hong, Ruoyu]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China
  • [ 4 ] [Chen, Jianguo]Fuzhou Univ, Coll Elect Engn & Automat, Fuzhou 350108, Peoples R China
  • [ 5 ] [Li, Minglin]Fuzhou Univ, Sch Mech Engn & Automat, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • [Hong, Ruoyu]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China;;[Li, Minglin]Fuzhou Univ, Sch Mech Engn & Automat, Fuzhou 350108, Peoples R China

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Source :

SURFACES AND INTERFACES

ISSN: 2468-0230

Year: 2025

Volume: 63

5 . 7 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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