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author:

Zhang, Jie (Zhang, Jie.) [1] (Scholars:章杰) | Li, Wangyang (Li, Wangyang.) [2] | Liu, Zongnian (Liu, Zongnian.) [3] | Huang, Zewei (Huang, Zewei.) [4] | Wang, Haiming (Wang, Haiming.) [5] | Ke, Bingyuan (Ke, Bingyuan.) [6] | Xue, Lu (Xue, Lu.) [7] | Jia, Hongjie (Jia, Hongjie.) [8] | Wang, Xinghui (Wang, Xinghui.) [9] (Scholars:王星辉)

Indexed by:

Scopus SCIE

Abstract:

All-solid-state batteries (ASSBs) with high-energy-density and enhanced safety are ideal for next-generation energy storage in electric transportation and Internet of Things. Fundamentally, the augmentation of their energy density relays on advanced cathode materials. This imperative has driven growing interest in Se-based cathodes, which demonstrate a high volumetric energy density, as well as higher electrical conductivity and better environmental adaptability compared to the well-known S cathodes. However, to ensure sufficient mechanical strength and mitigate the continuous deterioration of the solid-solid interface caused by the substantial volume expansion of the Se, the all-solid-state Li-Se batteries reported thus far typically employ thick solid electrolytes (50-200 mu m), which severely limits their energy density. Here, the first successful fabrication of all-solid-state thin-film Li-Se batteries is reported, featuring an ultra-thin (approximate to 1.4 mu m) lithium phosphorus oxynitride solid electrolyte and a hybrid Se cathode supported by vertical graphene nanoarrays (VGs). The conductive VGs, serving as the Se host, effectively mitigate the volume change during cycling and ensure stable solid-solid contact. Consequently, the cells exhibit over 1000 stable cycles with a capacity retention rate of 89% are attained in the "all-thin film" configuration. This study provides a novel design strategy for the development of next-generation high-performance ASSBs.

Keyword:

all-solid-state battery graphene nanoarrays Li-Se battery lithium phosphorous oxynitride Se cathode

Community:

  • [ 1 ] [Zhang, Jie]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Li, Wangyang]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 3 ] [Liu, Zongnian]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 4 ] [Huang, Zewei]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 5 ] [Wang, Haiming]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 6 ] [Ke, Bingyuan]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 7 ] [Xue, Lu]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 8 ] [Jia, Hongjie]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 9 ] [Wang, Xinghui]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 10 ] [Li, Wangyang]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Fujian, Peoples R China
  • [ 11 ] [Wang, Xinghui]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Fujian, Peoples R China
  • [ 12 ] [Li, Wangyang]Jiangsu Collaborat Innovat Ctr Photovolta Sci & En, Changzhou 213000, Peoples R China
  • [ 13 ] [Wang, Xinghui]Jiangsu Collaborat Innovat Ctr Photovolta Sci & En, Changzhou 213000, Peoples R China

Reprint 's Address:

  • 李王阳 王星辉

    [Li, Wangyang]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China;;[Wang, Xinghui]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China;;[Li, Wangyang]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Fujian, Peoples R China;;[Wang, Xinghui]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Fujian, Peoples R China;;[Li, Wangyang]Jiangsu Collaborat Innovat Ctr Photovolta Sci & En, Changzhou 213000, Peoples R China;;[Wang, Xinghui]Jiangsu Collaborat Innovat Ctr Photovolta Sci & En, Changzhou 213000, Peoples R China

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ADVANCED FUNCTIONAL MATERIALS

ISSN: 1616-301X

Year: 2025

1 8 . 5 0 0

JCR@2023

Cited Count:

WoS CC Cited Count: 1

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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