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author:

Wang, L. (Wang, L..) [1] | Yan, J. (Yan, J..) [2] | Yuan, J. (Yuan, J..) [3] | Lau, K.Y. (Lau, K.Y..) [4] | Dong, J. (Dong, J..) [5] | Zheng, J. (Zheng, J..) [6] | Xu, B. (Xu, B..) [7] | Yusoff, N.M. (Yusoff, N.M..) [8] | Mahdi, M.A. (Mahdi, M.A..) [9] | Qiao, Y. (Qiao, Y..) [10] | Zhang, Z. (Zhang, Z..) [11] | Qiu, J. (Qiu, J..) [12] | Liu, X. (Liu, X..) [13]

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Scopus

Abstract:

The intriguing optical response associated with the vanishingly small dielectric primitivity in epsilon-near-zero (ENZ) materials has offered unprecedented opportunities for photonics. Due to the high-limit of doping concentration, current homogeneous ENZ materials based on heavily doped conductive oxide including ITO usually exhibit a zero-permittivity wavelength (λ0) longer than 1200 nm. Here, this is identified with combined theoretical and experimental investigations that stoichiometric rutile-type RuO2 (r-RuO2) exhibits the shortest λ0 of near 800 nm among conductive oxides, benefiting from the high free electron concentration with characteristic Drude-type response. The ENZ effect is manifested by the strong field enhancement and the large nonlinear optical (NLO) response in colloidal processed r-RuO2 nanoparticles (NPs) and thin films. By ultrafast transient spectroscopy, the strong NLO response in r-RuO2 NPs is revealed to be the result of rapid thermalization/cooling of free electrons in the strong hybridized Ru-4d/O-2p orbitals. The ultrafast optical nonlinearity is exploited further for the development of multi-purpose all-optical switches that enable stable pulse laser generation in four mode-locked and Q-switched fiber lasers. Our results underscore the potential of stoichiometric metallic metal oxides as alternative ENZ materials for nonlinear photonics applications in the visible and NIR regions. © 2025 Wiley-VCH GmbH.

Keyword:

epsilon-near-zero medium nonlinear optical response optical switch RuO2

Community:

  • [ 1 ] [Wang L.]School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027, China
  • [ 2 ] [Yan J.]School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027, China
  • [ 3 ] [Yuan J.]Advanced Photonics Technology Lab, College of Electronics and Optical Engineering & College of Microelectronics, Nanjing University of Posts and Telecommunications, Nanjing, 210023, China
  • [ 4 ] [Lau K.Y.]School of Optoelectronic Science and Engineering & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, 215006, China
  • [ 5 ] [Dong J.]School of Material Science and Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 6 ] [Zheng J.]School of Material Science and Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 7 ] [Xu B.]State Key Lab of Modern Optical Instrumentation, College of Optical Science and Engineering, Zhejiang University, Hangzhou, 310027, China
  • [ 8 ] [Yusoff N.M.]Institute of Nanoscience and Nanotechnology (ION2), University Putra Malaysia, Selangor, Serdang, 43400, Malaysia
  • [ 9 ] [Mahdi M.A.]State Key Lab of Modern Optical Instrumentation, College of Optical Science and Engineering, Zhejiang University, Hangzhou, 310027, China
  • [ 10 ] [Qiao Y.]Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai, 201800, China
  • [ 11 ] [Zhang Z.]Advanced Photonics Technology Lab, College of Electronics and Optical Engineering & College of Microelectronics, Nanjing University of Posts and Telecommunications, Nanjing, 210023, China
  • [ 12 ] [Qiu J.]State Key Lab of Modern Optical Instrumentation, College of Optical Science and Engineering, Zhejiang University, Hangzhou, 310027, China
  • [ 13 ] [Liu X.]School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027, China

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Source :

Laser and Photonics Reviews

ISSN: 1863-8880

Year: 2025

Issue: 8

Volume: 19

9 . 8 0 0

JCR@2023

Cited Count:

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SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

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Chinese Cited Count:

30 Days PV: 0

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