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The intriguing optical response associated with the vanishingly small dielectric primitivity in epsilon-near-zero (ENZ) materials has offered unprecedented opportunities for photonics. Due to the high-limit of doping concentration, current homogeneous ENZ materials based on heavily doped conductive oxide including ITO usually exhibit a zero-permittivity wavelength (lambda(0)) longer than 1200 nm. Here, this is identified with combined theoretical and experimental investigations that stoichiometric rutile-type RuO2 (r-RuO2) exhibits the shortest lambda(0) of near 800 nm among conductive oxides, benefiting from the high free electron concentration with characteristic Drude-type response. The ENZ effect is manifested by the strong field enhancement and the large nonlinear optical (NLO) response in colloidal processed r-RuO2 nanoparticles (NPs) and thin films. By ultrafast transient spectroscopy, the strong NLO response in r-RuO2 NPs is revealed to be the result of rapid thermalization/cooling of free electrons in the strong hybridized Ru-4d/O-2p orbitals. The ultrafast optical nonlinearity is exploited further for the development of multi-purpose all-optical switches that enable stable pulse laser generation in four mode-locked and Q-switched fiber lasers. Our results underscore the potential of stoichiometric metallic metal oxides as alternative ENZ materials for nonlinear photonics applications in the visible and NIR regions.
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LASER & PHOTONICS REVIEWS
ISSN: 1863-8880
Year: 2025
Issue: 8
Volume: 19
9 . 8 0 0
JCR@2023
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 0
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