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author:

Wang, Lin (Wang, Lin.) [1] | Yan, Jiahe (Yan, Jiahe.) [2] | Yuan, Jiaqi (Yuan, Jiaqi.) [3] | Lau, Kuen Yao (Lau, Kuen Yao.) [4] | Dong, Junhao (Dong, Junhao.) [5] | Zheng, Jingying (Zheng, Jingying.) [6] | Xu, Beibei (Xu, Beibei.) [7] | Yusoff, Norita Mohd (Yusoff, Norita Mohd.) [8] | Mahdi, Mohd Adzir (Mahdi, Mohd Adzir.) [9] | Qiao, Yanbo (Qiao, Yanbo.) [10] | Zhang, Zuxing (Zhang, Zuxing.) [11] | Qiu, Jianrong (Qiu, Jianrong.) [12] | Liu, Xiaofeng (Liu, Xiaofeng.) [13]

Indexed by:

EI Scopus SCIE

Abstract:

The intriguing optical response associated with the vanishingly small dielectric primitivity in epsilon-near-zero (ENZ) materials has offered unprecedented opportunities for photonics. Due to the high-limit of doping concentration, current homogeneous ENZ materials based on heavily doped conductive oxide including ITO usually exhibit a zero-permittivity wavelength (lambda(0)) longer than 1200 nm. Here, this is identified with combined theoretical and experimental investigations that stoichiometric rutile-type RuO2 (r-RuO2) exhibits the shortest lambda(0) of near 800 nm among conductive oxides, benefiting from the high free electron concentration with characteristic Drude-type response. The ENZ effect is manifested by the strong field enhancement and the large nonlinear optical (NLO) response in colloidal processed r-RuO2 nanoparticles (NPs) and thin films. By ultrafast transient spectroscopy, the strong NLO response in r-RuO2 NPs is revealed to be the result of rapid thermalization/cooling of free electrons in the strong hybridized Ru-4d/O-2p orbitals. The ultrafast optical nonlinearity is exploited further for the development of multi-purpose all-optical switches that enable stable pulse laser generation in four mode-locked and Q-switched fiber lasers. Our results underscore the potential of stoichiometric metallic metal oxides as alternative ENZ materials for nonlinear photonics applications in the visible and NIR regions.

Keyword:

epsilon-near-zero medium nonlinear optical response optical switch RuO2

Community:

  • [ 1 ] [Wang, Lin]Zhejiang Univ, Sch Mat Sci & Engn, Hangzhou 310027, Peoples R China
  • [ 2 ] [Yan, Jiahe]Zhejiang Univ, Sch Mat Sci & Engn, Hangzhou 310027, Peoples R China
  • [ 3 ] [Liu, Xiaofeng]Zhejiang Univ, Sch Mat Sci & Engn, Hangzhou 310027, Peoples R China
  • [ 4 ] [Yuan, Jiaqi]Nanjing Univ Posts & Telecommun, Coll Elect & Opt Engn, Adv Photon Technol Lab, Nanjing 210023, Peoples R China
  • [ 5 ] [Zhang, Zuxing]Nanjing Univ Posts & Telecommun, Coll Elect & Opt Engn, Adv Photon Technol Lab, Nanjing 210023, Peoples R China
  • [ 6 ] [Yuan, Jiaqi]Nanjing Univ Posts & Telecommun, Coll Microelect, Nanjing 210023, Peoples R China
  • [ 7 ] [Zhang, Zuxing]Nanjing Univ Posts & Telecommun, Coll Microelect, Nanjing 210023, Peoples R China
  • [ 8 ] [Lau, Kuen Yao]Soochow Univ, Sch Optoelect Sci & Engn, Suzhou 215006, Peoples R China
  • [ 9 ] [Lau, Kuen Yao]Soochow Univ, Collaborat Innovat Ctr Suzhou Nano Sci & Technol, Suzhou 215006, Peoples R China
  • [ 10 ] [Dong, Junhao]Fuzhou Univ, Sch Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 11 ] [Zheng, Jingying]Fuzhou Univ, Sch Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 12 ] [Xu, Beibei]Zhejiang Univ, Coll Opt Sci & Engn, State Key Lab Modern Opt Instrumentat, Hangzhou 310027, Peoples R China
  • [ 13 ] [Mahdi, Mohd Adzir]Zhejiang Univ, Coll Opt Sci & Engn, State Key Lab Modern Opt Instrumentat, Hangzhou 310027, Peoples R China
  • [ 14 ] [Qiu, Jianrong]Zhejiang Univ, Coll Opt Sci & Engn, State Key Lab Modern Opt Instrumentat, Hangzhou 310027, Peoples R China
  • [ 15 ] [Yusoff, Norita Mohd]Univ Putra Malaysia, Inst Nanosci & Nanotechnol ION2, Serdang 43400, Selangor, Malaysia
  • [ 16 ] [Qiao, Yanbo]Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China

Reprint 's Address:

  • [Liu, Xiaofeng]Zhejiang Univ, Sch Mat Sci & Engn, Hangzhou 310027, Peoples R China;;[Zhang, Zuxing]Nanjing Univ Posts & Telecommun, Coll Elect & Opt Engn, Adv Photon Technol Lab, Nanjing 210023, Peoples R China;;[Zhang, Zuxing]Nanjing Univ Posts & Telecommun, Coll Microelect, Nanjing 210023, Peoples R China;;[Lau, Kuen Yao]Soochow Univ, Sch Optoelect Sci & Engn, Suzhou 215006, Peoples R China;;[Lau, Kuen Yao]Soochow Univ, Collaborat Innovat Ctr Suzhou Nano Sci & Technol, Suzhou 215006, Peoples R China

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Source :

LASER & PHOTONICS REVIEWS

ISSN: 1863-8880

Year: 2025

Issue: 8

Volume: 19

9 . 8 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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