An Organic EnT Photocatalyst 4CzMeBN and the Application in the Synthesis of cis-Fused Azetidines - Details

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Abstract：

A　powerful　EnT　photocatalyst　4CzMeBN　has　been　developed　and　utilized　in　the　synthesis　of　cis-fused　azetidines　via　dearomative　[2+2]　cycloaddition　under　visible　light.　The　photocatalyst　4CzMeBN　is　a　donor-acceptor　cyanoarene　and　features　high　triplet　state　energy　and　long　lifetime　of　triplet　state,　which　would　be　an　alternative　to　widely　used　EnT　photocatalyst　Ir[dF(CF3)ppy]2(dtbbpy)PF6.　The　photochemical　[2+2]　cycloaddition　provides　a　facile　method　to　synthesize　valuable　dihydroisoquinolone-fused　azetidines　with　high　efficiency.　©　2024　Wiley-VCH　GmbH.

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[2+2] Cycloaddition 4CzMeBN Azetidines EnT photocatalyst Isoquinolone

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[ 1 ] [Feng C.]Nuclear Medicine and Molecular Imaging Key Laboratory of Sichuan Province, School of Pharmacy, Southwest Medical University, Luzhou, 646000, China
[ 2 ] [Liu Y.]Nuclear Medicine and Molecular Imaging Key Laboratory of Sichuan Province, School of Pharmacy, Southwest Medical University, Luzhou, 646000, China
[ 3 ] [Xiang Z.]Nuclear Medicine and Molecular Imaging Key Laboratory of Sichuan Province, School of Pharmacy, Southwest Medical University, Luzhou, 646000, China
[ 4 ] [Cheng X.]Nuclear Medicine and Molecular Imaging Key Laboratory of Sichuan Province, School of Pharmacy, Southwest Medical University, Luzhou, 646000, China
[ 5 ] [Wei S.]Nuclear Medicine and Molecular Imaging Key Laboratory of Sichuan Province, School of Pharmacy, Southwest Medical University, Luzhou, 646000, China
[ 6 ] [Wei S.]State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350116, China
[ 7 ] [Liu X.]Nuclear Medicine and Molecular Imaging Key Laboratory of Sichuan Province, School of Pharmacy, Southwest Medical University, Luzhou, 646000, China
[ 8 ] [Deng Q.]Nuclear Medicine and Molecular Imaging Key Laboratory of Sichuan Province, School of Pharmacy, Southwest Medical University, Luzhou, 646000, China
[ 9 ] [Fu Q.]Nuclear Medicine and Molecular Imaging Key Laboratory of Sichuan Province, School of Pharmacy, Southwest Medical University, Luzhou, 646000, China
[ 10 ] [Zhang Z.]Nuclear Medicine and Molecular Imaging Key Laboratory of Sichuan Province, School of Pharmacy, Southwest Medical University, Luzhou, 646000, China
[ 11 ] [Zhang Z.]State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350116, China
[ 12 ] [Zhang Z.]Central Nervous System Drug Key Laboratory of Sichuan Province, Luzhou, 646000, China

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An Organic EnT Photocatalyst 4CzMeBN and the Application in the Synthesis of cis-Fused Azetidines
2024，CHEMISTRY-A EUROPEAN JOURNAL
Cobalt-catalyzed amination of aziridines and azetidines toward 1,2-and 1,3-diamines
2024，ORGANIC & BIOMOLECULAR CHEMISTRY

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Chemistry - A European Journal

ISSN： 0947-6539

Year： 2024

3 . 9 0 0

JCR@2023

CAS Journal Grade：3

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SCOPUS Cited Count： 1

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30 Days PV： 4

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