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Abstract:
A powerful EnT photocatalyst 4CzMeBN has been developed and utilized in the synthesis of cis-fused azetidines via dearomative [2+2] cycloaddition under visible light. The photocatalyst 4CzMeBN is a donor-acceptor cyanoarene and features high triplet state energy and long lifetime of triplet state, which would be an alternative to widely used EnT photocatalyst Ir[dF(CF3)ppy]2(dtbbpy)PF6. The photochemical [2+2] cycloaddition provides a facile method to synthesize valuable dihydroisoquinolone-fused azetidines with high efficiency.
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CHEMISTRY-A EUROPEAN JOURNAL
ISSN: 0947-6539
Year: 2024
3 . 9 0 0
JCR@2023
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 0
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